Email this article Influence of Chemical Modification on the Structure, Composition, and Properties of Lignite Humic Acids
- Authors: Zherebtsov S.I.1, Malyshenko N.V.1, Bryukhovetskaya L.V.1, Lyrshchikov S.Y.1, Nikitin A.P.1, Ismagilov Z.R.1
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Affiliations:
- Federal Research Center of Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences
- Issue: Vol 61, No 10 (2018)
- Pages: 396-400
- Section: Chemistry
- URL: https://ogarev-online.ru/1068-364X/article/view/226638
- DOI: https://doi.org/10.3103/S1068364X18100083
- ID: 226638
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Abstract
The influence of chemical modification on the functional–group composition of humic acids derived from Tisul’sk lignite (Kansko-Achinsk Basin) is studied. The structural changes of the humic acids as a result of destructive alkylation of n-butanol and oxidation of hydrogen peroxide are compared, by means of IR, Raman, ESR, and NMR spectroscopy. Alkylation of the humic acids changes the composition and content of the aliphatic fragments in their structure. Oxidation by hydrogen peroxide increases the content of acid-bearing groups.
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About the authors
S. I. Zherebtsov
Federal Research Center of Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences
Author for correspondence.
Email: sizh@yandex.ru
Russian Federation, Kemerovo
N. V. Malyshenko
Federal Research Center of Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences
Author for correspondence.
Email: profkemsc@yandex.ru
Russian Federation, Kemerovo
L. V. Bryukhovetskaya
Federal Research Center of Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences
Author for correspondence.
Email: blv3010@mail.ru
Russian Federation, Kemerovo
S. Yu. Lyrshchikov
Federal Research Center of Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences
Author for correspondence.
Email: serstud@mail.ru
Russian Federation, Kemerovo
A. P. Nikitin
Federal Research Center of Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences
Author for correspondence.
Email: NikitinAndrey@yandex.ru
Russian Federation, Kemerovo
Z. R. Ismagilov
Federal Research Center of Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences
Author for correspondence.
Email: zinfer1@mail.ru
Russian Federation, Kemerovo
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