Energetic abilities of nitro derivatives of isomeric (pyrazol-3-yl)tetrazoles as components of solid composite propellants
- 作者: Lempert D.B.1, Kazakov A.I.1, Soglasnova S.I.1, Dalinger I.L.2, Sheremetev A.B.2
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隶属关系:
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- 期: 卷 67, 编号 9 (2018)
- 页面: 1580-1588
- 栏目: Article
- URL: https://ogarev-online.ru/1066-5285/article/view/242951
- DOI: https://doi.org/10.1007/s11172-018-2261-x
- ID: 242951
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详细
Theoretical estimation of the efficiency factors of solid propellants whose components are CHNO compounds designed from various combinations of four structural motifs, namely pyrazole and tetrazole rings, nitro group, and trinitromethyl moiety, was performed. The positional isomerism was shown to have effect on the properties of the compounds and the energy characteristics of solid composite propellants (SCPs) on their basis. The use of these components in metal-free SCP compositions can allow one to achieve a specific impulse of 258–263 s, neither toxic HCl nor condensed products being produced upon their combustion, i.e., they are superior in energy and environmental indices to SCP formulations based on ammonium perchlorate.
作者简介
D. Lempert
Institute of Problems of Chemical Physics, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: lempert@icp.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
A. Kazakov
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: sab@ioc.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
S. Soglasnova
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: sab@ioc.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
I. Dalinger
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: sab@ioc.ac.ru
俄罗斯联邦, 47 Leninskii prosp., Moscow, 119991
A. Sheremetev
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: sab@ioc.ac.ru
俄罗斯联邦, 47 Leninskii prosp., Moscow, 119991
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