Decay of H2O2 under the action of the colloidal catalyst based on iron(III) oxides in a neutral medium


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The catalytic activity of the colloidal catalyst based on iron(III) hydroxide was studied in the decomposition of H2O2 in a neutral medium (pH 6.7). A colloidal micellar solution of iron(III) hydroxide after preparation was kept at 19–20 °С for 2 or 20 h without additives or with C2H5OH additives. The decomposition of H2O2 under the action of the colloidal catalyst (20 h) proceeds via the first-order reaction with the decay rate constant kd = 1.26•10–4 s–1, whereas the decay rate of the first-order reaction is kd = 0.77•10–4 s–1 for the colloidal catalyst (2 h) prepared in the presence of C2H5OH.

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L. Pisarenko

N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences

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Email: pissarenkolm@mail.ru
俄罗斯联邦, 4 ul. Kosygina, Moscow, 119991

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