Selective aqueous-phase hydrogenation of furfural to cyclopentanol over PdRu/C catalyst


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The bimetallic PdRu catalyst supported on carbon nanotubes were found ot provide an efficient synthesis of cyclopentanol in aqueous-phase hydrogenation of furfural. Under the chosen reaction conditions (temperature of 473 K, total pressure of 8 MPa), the selectivity towards cyclopentanol reaches 77% at a complete conversion of furfural. A high activity of this catalyst can be associated with changes in the electronic state and dispersion of the supported metals caused by their mutual interaction and formation of PdRu alloy.

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R. Mironenko

Institute of Hydrocarbons Processing, Siberian Branch of the Russian Academy of Sciences; Dostoevsky Omsk State University

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Email: ch-mrm@mail.ru
俄罗斯联邦, 54 ul. Neftezavodskaya, Omsk, 644040; 55a prosp. Mira, Omsk, 644077

O. Belskaya

Institute of Hydrocarbons Processing, Siberian Branch of the Russian Academy of Sciences; Omsk State Technical University

Email: ch-mrm@mail.ru
俄罗斯联邦, 54 ul. Neftezavodskaya, Omsk, 644040; 11 prosp. Mira, Omsk, 644050

A. Lavrenov

Institute of Hydrocarbons Processing, Siberian Branch of the Russian Academy of Sciences

Email: ch-mrm@mail.ru
俄罗斯联邦, 54 ul. Neftezavodskaya, Omsk, 644040

V. Likholobov

Institute of Hydrocarbons Processing, Siberian Branch of the Russian Academy of Sciences; Omsk State Technical University; Omsk Scientific Center, Siberian Branch of the Russian Academy of Sciences

Email: ch-mrm@mail.ru
俄罗斯联邦, 54 ul. Neftezavodskaya, Omsk, 644040; 11 prosp. Mira, Omsk, 644050; 15 prosp. Marksa, Omsk, 644024

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