Selective aqueous-phase hydrogenation of furfural to cyclopentanol over PdRu/C catalyst


Дәйексөз келтіру

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Рұқсат жабық Тек жазылушылар үшін

Аннотация

The bimetallic PdRu catalyst supported on carbon nanotubes were found ot provide an efficient synthesis of cyclopentanol in aqueous-phase hydrogenation of furfural. Under the chosen reaction conditions (temperature of 473 K, total pressure of 8 MPa), the selectivity towards cyclopentanol reaches 77% at a complete conversion of furfural. A high activity of this catalyst can be associated with changes in the electronic state and dispersion of the supported metals caused by their mutual interaction and formation of PdRu alloy.

Авторлар туралы

R. Mironenko

Institute of Hydrocarbons Processing, Siberian Branch of the Russian Academy of Sciences; Dostoevsky Omsk State University

Хат алмасуға жауапты Автор.
Email: ch-mrm@mail.ru
Ресей, 54 ul. Neftezavodskaya, Omsk, 644040; 55a prosp. Mira, Omsk, 644077

O. Belskaya

Institute of Hydrocarbons Processing, Siberian Branch of the Russian Academy of Sciences; Omsk State Technical University

Email: ch-mrm@mail.ru
Ресей, 54 ul. Neftezavodskaya, Omsk, 644040; 11 prosp. Mira, Omsk, 644050

A. Lavrenov

Institute of Hydrocarbons Processing, Siberian Branch of the Russian Academy of Sciences

Email: ch-mrm@mail.ru
Ресей, 54 ul. Neftezavodskaya, Omsk, 644040

V. Likholobov

Institute of Hydrocarbons Processing, Siberian Branch of the Russian Academy of Sciences; Omsk State Technical University; Omsk Scientific Center, Siberian Branch of the Russian Academy of Sciences

Email: ch-mrm@mail.ru
Ресей, 54 ul. Neftezavodskaya, Omsk, 644040; 11 prosp. Mira, Omsk, 644050; 15 prosp. Marksa, Omsk, 644024

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