A mechanistic study of arabinigalactan sulfation with potassium persulfate in dimethyl sulfoxide
- Авторы: Kostyro Y.A.1, Smirnov V.I.1, Sinegovskaya L.M.1, Vakul’skaya T.I.1, Khutsishvili S.S.1
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Учреждения:
- A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
- Выпуск: Том 66, № 12 (2017)
- Страницы: 2317-2320
- Раздел: Full Article
- URL: https://ogarev-online.ru/1066-5285/article/view/241837
- DOI: https://doi.org/10.1007/s11172-017-2022-2
- ID: 241837
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Аннотация
The mechanism of polysaccharide arabinogalactan sulfation was studied. Potassium persulfate in dimethyl sulfoxide was used as a sulfating agent. Sulfation of the biopolymer proceeds via its reaction with the SO3—DMSO complex, which is formed upon the reduction of the persulfate anion in DMSO.
Об авторах
Ya. Kostyro
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Автор, ответственный за переписку.
Email: yanakos@irioch.irk.ru
Россия, 1 ul. Favorskogo, Irkutsk, 664033
V. Smirnov
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: yanakos@irioch.irk.ru
Россия, 1 ul. Favorskogo, Irkutsk, 664033
L. Sinegovskaya
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: yanakos@irioch.irk.ru
Россия, 1 ul. Favorskogo, Irkutsk, 664033
T. Vakul’skaya
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: yanakos@irioch.irk.ru
Россия, 1 ul. Favorskogo, Irkutsk, 664033
S. Khutsishvili
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: yanakos@irioch.irk.ru
Россия, 1 ul. Favorskogo, Irkutsk, 664033
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