Synthesis of gem-dichlorocyclopropane and 1,3-dioxane derivatives from divinylbenzene
- Autores: Raskil’dina G.Z.1, Borisova Y.G.1, Spirikhin L.V.2, Zlotskii S.S.1
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Afiliações:
- Ufa State Petroleum Technological University
- Ufa Federal Research Centre of the Russian Academy of Sciences
- Edição: Volume 68, Nº 11 (2019)
- Páginas: 2092-2097
- Seção: Full Articles
- URL: https://ogarev-online.ru/1066-5285/article/view/243532
- DOI: https://doi.org/10.1007/s11172-019-2671-4
- ID: 243532
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Resumo
The Prins reaction and cyclopropanation of the light fraction obtained by distillation of the technical grade divinylbenzene and consisting of a mixture of 1,3- and 1,4-divinylbenzenes with admixture of 3- and 4-ethylstyrenes were studied. These reactions quantitatively give the corresponding gem-dichlorocyclopropane and 1,3-dioxane benzene derivatives. The structures of the synthesized compounds were confirmed by NMR spectroscopy and mass spectrometry.
Sobre autores
G. Raskil’dina
Ufa State Petroleum Technological University
Autor responsável pela correspondência
Email: graskildina444@mail.ru
Rússia, 1 ul. Kosmonavtov, Ufa, 450062
Yu. Borisova
Ufa State Petroleum Technological University
Email: spectr@anrb.ru
Rússia, 1 ul. Kosmonavtov, Ufa, 450062
L. Spirikhin
Ufa Federal Research Centre of the Russian Academy of Sciences
Autor responsável pela correspondência
Email: spectr@anrb.ru
Rússia, 71 prosp. Oktyabrya, Ufa, Bashkortostan, 450054
S. Zlotskii
Ufa State Petroleum Technological University
Email: spectr@anrb.ru
Rússia, 1 ul. Kosmonavtov, Ufa, 450062
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