Synthesis of gem-dichlorocyclopropane and 1,3-dioxane derivatives from divinylbenzene


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The Prins reaction and cyclopropanation of the light fraction obtained by distillation of the technical grade divinylbenzene and consisting of a mixture of 1,3- and 1,4-divinylbenzenes with admixture of 3- and 4-ethylstyrenes were studied. These reactions quantitatively give the corresponding gem-dichlorocyclopropane and 1,3-dioxane benzene derivatives. The structures of the synthesized compounds were confirmed by NMR spectroscopy and mass spectrometry.

Sobre autores

G. Raskil’dina

Ufa State Petroleum Technological University

Autor responsável pela correspondência
Email: graskildina444@mail.ru
Rússia, 1 ul. Kosmonavtov, Ufa, 450062

Yu. Borisova

Ufa State Petroleum Technological University

Email: spectr@anrb.ru
Rússia, 1 ul. Kosmonavtov, Ufa, 450062

L. Spirikhin

Ufa Federal Research Centre of the Russian Academy of Sciences

Autor responsável pela correspondência
Email: spectr@anrb.ru
Rússia, 71 prosp. Oktyabrya, Ufa, Bashkortostan, 450054

S. Zlotskii

Ufa State Petroleum Technological University

Email: spectr@anrb.ru
Rússia, 1 ul. Kosmonavtov, Ufa, 450062

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