Enviar artigo por via de e-mail A new approach to the study of the structure of polyisoprene obtained by cationic polymerization
- Autores: Rozentsvet V.A.1, Kozlov V.G.1, Stotskaya O.A.1, Smirnov S.N.2, Tolstoy P.M.2
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Afiliações:
- Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
- St.-Petersburg State University, Department of Chemistry
- Edição: Volume 68, Nº 1 (2019)
- Páginas: 116-120
- Seção: Full Articles
- URL: https://ogarev-online.ru/1066-5285/article/view/243286
- DOI: https://doi.org/10.1007/s11172-019-2425-3
- ID: 243286
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Resumo
The use of the T2 filter in NMR studies allowed us to separate carbon atoms by their mobility in different fragments of the macromolecular chain of polyisoprene synthesized by cationic polymerization. The NMR signals of terminal units with conjugated double bonds were identified for the first time for the “cationic” polyisoprene, which experimentally confirmed the transfer of the growing chain to the monomer in the process of cationic polymerization of isoprene.
Sobre autores
V. Rozentsvet
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
Autor responsável pela correspondência
Email: rozentsvet@mail.ru
Rússia, 10 ul. Komzina, Togliatti, 445003
V. Kozlov
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
Email: rozentsvet@mail.ru
Rússia, 10 ul. Komzina, Togliatti, 445003
O. Stotskaya
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
Email: rozentsvet@mail.ru
Rússia, 10 ul. Komzina, Togliatti, 445003
S. Smirnov
St.-Petersburg State University, Department of Chemistry
Email: rozentsvet@mail.ru
Rússia, 7–9 Universitetskaya nab., St.-Petersburg, 199034
P. Tolstoy
St.-Petersburg State University, Department of Chemistry
Email: rozentsvet@mail.ru
Rússia, 7–9 Universitetskaya nab., St.-Petersburg, 199034
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