(2Z)-2,3,4,5,5-Pentachloropenta-2,4-dienic acid as a minor product in the synthesis of 5,5-dimetoxytetrachlorocyclopentadiene from hexachlorocyclopentadiene


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Аннотация

Pentachloropentadienic acid was isolated, apart from the expected 5,5-dimetoxytetrachlorocyclopentadiene, in the reaction of hexachlorocyclopentadiene with potassium hydroxide in methanol. The structure of this minor product was established by X-ray crystallography. The plausible mechanism of its formation is discussed.

Авторлар туралы

V. Egorov

Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences

Email: bioreg@anrb.ru
Ресей, 69 prosp. Oktyabrya, Ufa, Bashkortostan, 450054

L. Khalilov

Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences

Email: bioreg@anrb.ru
Ресей, 141 prosp. Oktyabrya, Ufa, Bashkortostan, 450075

F. Gimalova

Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences

Email: bioreg@anrb.ru
Ресей, 69 prosp. Oktyabrya, Ufa, Bashkortostan, 450054

M. Miftakhov

Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: bioreg@anrb.ru
Ресей, 69 prosp. Oktyabrya, Ufa, Bashkortostan, 450054

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