Email this article (2Z)-2,3,4,5,5-Pentachloropenta-2,4-dienic acid as a minor product in the synthesis of 5,5-dimetoxytetrachlorocyclopentadiene from hexachlorocyclopentadiene
- Authors: Egorov V.A.1, Khalilov L.M.2, Gimalova F.A.1, Miftakhov M.S.1
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Affiliations:
- Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences
- Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences
- Issue: Vol 68, No 10 (2019)
- Pages: 1940-1943
- Section: Brief Communications
- URL: https://ogarev-online.ru/1066-5285/article/view/243511
- DOI: https://doi.org/10.1007/s11172-019-2650-9
- ID: 243511
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Abstract
Pentachloropentadienic acid was isolated, apart from the expected 5,5-dimetoxytetrachlorocyclopentadiene, in the reaction of hexachlorocyclopentadiene with potassium hydroxide in methanol. The structure of this minor product was established by X-ray crystallography. The plausible mechanism of its formation is discussed.
About the authors
V. A. Egorov
Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences
Email: bioreg@anrb.ru
Russian Federation, 69 prosp. Oktyabrya, Ufa, Bashkortostan, 450054
L. M. Khalilov
Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences
Email: bioreg@anrb.ru
Russian Federation, 141 prosp. Oktyabrya, Ufa, Bashkortostan, 450075
F. A. Gimalova
Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences
Email: bioreg@anrb.ru
Russian Federation, 69 prosp. Oktyabrya, Ufa, Bashkortostan, 450054
M. S. Miftakhov
Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences
Author for correspondence.
Email: bioreg@anrb.ru
Russian Federation, 69 prosp. Oktyabrya, Ufa, Bashkortostan, 450054
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