Email this article Complexes of palladium(II) with N-heterocyclic carbenes from adamantylimidazole as precatalysts for thiophene and imidazole arylation
- Authors: Denisov M.S.1, Dmitriev M.V.2, Gorbunov A.A.1, Glushkov V.A.1,2
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Affiliations:
- Institute of Technical Chemistry, Perm Federal Scientific Center, Ural Branch of the Russian Academy of Sciences
- Perm State National Research University
- Issue: Vol 68, No 11 (2019)
- Pages: 2039-2047
- Section: Full Articles
- URL: https://ogarev-online.ru/1066-5285/article/view/243525
- DOI: https://doi.org/10.1007/s11172-019-2664-3
- ID: 243525
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Abstract
Complexes of palladium(II) with N-heterocyclic carbenes of the PEPPSI-type were synthesized by the reaction of PdCl2 with 1-adamantyl-3-(R-methyl)-1H-imidazolium salts. These complexes were used as productive precatalysts for substituted thiophene and imidazole arylation by C—H-activation.
About the authors
M. S. Denisov
Institute of Technical Chemistry, Perm Federal Scientific Center, Ural Branch of the Russian Academy of Sciences
Author for correspondence.
Email: denisov.m@itcras.ru
Russian Federation, 3 ul. Akad. Koroleva, Perm, 614013
M. V. Dmitriev
Perm State National Research University
Email: denisov.m@itcras.ru
Russian Federation, 5 ul. Bukireva, Perm, 614990
A. A. Gorbunov
Institute of Technical Chemistry, Perm Federal Scientific Center, Ural Branch of the Russian Academy of Sciences
Email: denisov.m@itcras.ru
Russian Federation, 3 ul. Akad. Koroleva, Perm, 614013
V. A. Glushkov
Institute of Technical Chemistry, Perm Federal Scientific Center, Ural Branch of the Russian Academy of Sciences; Perm State National Research University
Email: denisov.m@itcras.ru
Russian Federation, 3 ul. Akad. Koroleva, Perm, 614013; 5 ul. Bukireva, Perm, 614990
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