Email this article Interaction of perfluoropolyether peroxide PFPEP-4 with polyfluoroaromatic compounds
- Authors: Glazkov A.A.1, Yarosh A.A.1, Sakharov A.M.1
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Affiliations:
- N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- Issue: Vol 68, No 10 (2019)
- Pages: 1903-1907
- Section: Full Articles
- URL: https://ogarev-online.ru/1066-5285/article/view/243506
- DOI: https://doi.org/10.1007/s11172-019-2645-6
- ID: 243506
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Abstract
The interaction of perfluoropolyether peroxides with perfluoro- and polyfluoroaromatic compounds (C6F6, C6F5H, C6F5Cl, and C6F5CF3) was investigated. It was found that branched and cross-linked perfluoropolymers with a glass transition temperature below −110 °C and the destruction onset temperature 400 °C were generated under the thermolysis of perfluoropolyperoxides and polyfluorinated aromatic compounds at 280–290 °C. DSC and DTGA data were provided.
About the authors
A. A. Glazkov
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: yar@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
A. A. Yarosh
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: yar@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
A. M. Sakharov
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: yar@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
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