Silica gel modified with tetraalkylammonium halides as an available and efficient catalyst for the synthesis of cyclic organic carbonates from epoxides and CO 2

S. E. Lyubimov; M. V. Sokolovskaya; B. Chowdhury; A. V. Arzumanyan; R. S. Tukhvatshin; L. F. Ibragimova; A. A. Tyutyunov; V. A. Davankov; A. M. Muzafarov

doi:10.1007/s11172-019-2637-6

Silica gel modified with tetraalkylammonium halides as an available and efficient catalyst for the synthesis of cyclic organic carbonates from epoxides and CO₂

Authors: Lyubimov S.E.¹, Sokolovskaya M.V.¹, Chowdhury B.², Arzumanyan A.V.¹, Tukhvatshin R.S.¹, Ibragimova L.F.¹, Tyutyunov A.A.¹, Davankov V.A.¹, Muzafarov A.M.¹
Affiliations:
1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
2. Department of Applied Chemistry, Indian Institute of Technology (Indian School of Mines)
Issue: Vol 68, No 10 (2019)
Pages: 1866-1868
Section: Full Articles
URL: https://ogarev-online.ru/1066-5285/article/view/243498
DOI: https://doi.org/10.1007/s11172-019-2637-6
ID: 243498

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription Access

Abstract
About the authors
References
Supplementary files
Statistics

Abstract

Silica gel with the additives of tetraalkylammonium halides serves as an efficient catalyst for the solvent-free insertion of carbon dioxide into epoxides (10–56 atm of CO₂, 105–100 °C), leading to cyclic carbonates with quantitative conversion.