Email this article 1,2-Bis(diphenylphosphino)ethane-containing commo-ferracarboranes of unusual structure
- Authors: Balagurova E.V.1, Dolgushin F.M.1, Tyurin A.P.2, Smol’yakov A.F.1,3, Chizhevsky I.T.1
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Affiliations:
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Gause Institute of New Antibiotics
- Faculty of Science, Peoples’ Friendship University of Russia (RUDN University)
- Issue: Vol 68, No 8 (2019)
- Pages: 1542-1547
- Section: Full Article
- URL: https://ogarev-online.ru/1066-5285/article/view/243450
- DOI: https://doi.org/10.1007/s11172-019-2589-x
- ID: 243450
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Abstract
commo-Ferracarboranes and [8-{(nido-7″,8″-C2B9H11-9″(11″)-)Ph2PCH2CH2PPh2}-commo-3,3′-Fe-{1,2-C2H9B10}{1′2′-C2B9H11}] were prepared as minor products in the metallation reaction of [K]+[nido-7,8-C2B9H12]− with the 14-electron iron complex [Ph2P(CH2)2PPh2]FeCl2. The structures of the complexes were determined by single-crystal X-ray diffraction.
About the authors
E. V. Balagurova
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Author for correspondence.
Email: balena.ran@mail.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
F. M. Dolgushin
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: balena.ran@mail.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
A. P. Tyurin
Gause Institute of New Antibiotics
Email: balena.ran@mail.ru
Russian Federation, 11 ul. Bolshaya Pirogovskaya, Moscow, 119021
A. F. Smol’yakov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; Faculty of Science, Peoples’ Friendship University of Russia (RUDN University)
Email: balena.ran@mail.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991; 6 ul. Miklukho-Maklaya, Moscow, 117198
I. T. Chizhevsky
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: balena.ran@mail.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
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