Addition of N-hydroxyphthalimide and atmospheric oxygen to styrenes using tert-butyl hydroperoxide as a radical initiator


Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

1-Aryl-1-hydroperoxy-2-imidooxyethanes are selectively formed at room temperature from styrenes, N-hydroxyphthalimide, and atmospheric oxygen with the participation of tert-butyl hydroperoxide as a radical initiator.

About the authors

I. B. Krylov

N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Email: terentev@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991

A. S. Budnikov

N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences; D. I. Mendeleev University of Chemical Technology of Russia

Email: terentev@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991; 9 Miusskaya pl., Moscow, 125047

A. V. Lastovko

N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences; M. V. Lomonosov Moscow State University

Email: terentev@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991; 1 Leninskie Gory, Moscow, 119991

Y. A. Ibatov

N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences; D. I. Mendeleev University of Chemical Technology of Russia

Email: terentev@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991; 9 Miusskaya pl., Moscow, 125047

G. I. Nikishin

N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Email: terentev@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991

A. O. Terent′ev

N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences; D. I. Mendeleev University of Chemical Technology of Russia

Author for correspondence.
Email: terentev@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991; 9 Miusskaya pl., Moscow, 125047

Supplementary files

Supplementary Files
Action
1. JATS XML

Copyright (c) 2019 Springer Science+Business Media, LLC, part of Springer Nature