Email this article Reductive bromination of N, N-bis(4-tert-butylphenyl)hydroxylamine
- Authors: Golubev V.A.1, Kim Y.D.2
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Affiliations:
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- M. V. Lomonosov Moscow State University
- Issue: Vol 68, No 6 (2019)
- Pages: 1293-1297
- Section: Brief Communication
- URL: https://ogarev-online.ru/1066-5285/article/view/243417
- DOI: https://doi.org/10.1007/s11172-019-2556-6
- ID: 243417
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Abstract
Unlike most arenes, N, N-bis(4-tert-butylphenyl)hydroxylamine reacts with Br2via the reductive bromination mechanism. Here, two hydrogens in ortho positions of benzene rings are substituted by Br2 and provide two-electron reduction of hydroxylamine to amine.
About the authors
V. A. Golubev
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Author for correspondence.
Email: vgolubev@icp.ac.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
Yu. D. Kim
M. V. Lomonosov Moscow State University
Email: vgolubev@icp.ac.ru
Russian Federation, 1 Leninskie Gory, Moscow, 119991
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