Email this article Selective synthesis of cyclic triperoxides from 1,1′-dihydroperoxydi(cycloalkyl)peroxides and acetals using SnCl4
- Authors: Radulov P.S.1,2, Belyakova Y.Y.1, Demina A.A.3, Nikishin G.I.1, Yaremenko I.A.1,2,4, Terent’ev A.O.1,2,4
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Affiliations:
- N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences
- All-Russia Research Institute for Phytopathology
- M. V. Lomonosov Moscow State University
- D. I. Mendeleev University of Chemical Technology of Russia
- Issue: Vol 68, No 6 (2019)
- Pages: 1289-1292
- Section: Brief Communication
- URL: https://ogarev-online.ru/1066-5285/article/view/243416
- DOI: https://doi.org/10.1007/s11172-019-2555-7
- ID: 243416
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Abstract
A method for the synthesis of 1,2,4,5,7,8-hexaoxonanes by the reaction of 1,1′-dihydroperoxydi(cycloalkyl)peroxides with acetals using SnCl4 has been developed. For the first time, it was shown that SnCl4 can serve as an effective reagent for the synthesis of cyclic organic peroxides. The proposed method allows obtaining 9-membered cyclic triperoxides selectively and in the yields of up to 90% based on the isolated product.
About the authors
P. S. Radulov
N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences; All-Russia Research Institute for Phytopathology
Email: terentev@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991; 5 ul. Institut, Bolshie Vyazyomy, Odintsovo District, Moscow Region, 143050
Yu. Yu. Belyakova
N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences
Email: terentev@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
A. A. Demina
M. V. Lomonosov Moscow State University
Email: terentev@ioc.ac.ru
Russian Federation, 1-3 Leninskiye Gory, Moscow, 119991
G. I. Nikishin
N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences
Email: terentev@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
I. A. Yaremenko
N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences; All-Russia Research Institute for Phytopathology; D. I. Mendeleev University of Chemical Technology of Russia
Email: terentev@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991; 5 ul. Institut, Bolshie Vyazyomy, Odintsovo District, Moscow Region, 143050; 9 Miusskaya pl., Moscow, 125047
A. O. Terent’ev
N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences; All-Russia Research Institute for Phytopathology; D. I. Mendeleev University of Chemical Technology of Russia
Author for correspondence.
Email: terentev@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991; 5 ul. Institut, Bolshie Vyazyomy, Odintsovo District, Moscow Region, 143050; 9 Miusskaya pl., Moscow, 125047
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