Email this article Nitrosylsulfuric acid as a tandem reagent in the synthesis of 3,5-diarylisoxazoles from 1,2-diarylcyclopropanes
- Authors: Bondarenko O.B.1, Komarov A.I.1, Karetnikov G.L.1, Nikolaeva S.N.1, Zyk N.V.1
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Affiliations:
- Department of Chemistry, M. V. Lomonosov Moscow State University
- Issue: Vol 68, No 6 (2019)
- Pages: 1200-1203
- Section: Full Article
- URL: https://ogarev-online.ru/1066-5285/article/view/243401
- DOI: https://doi.org/10.1007/s11172-019-2540-1
- ID: 243401
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Abstract
It was demonstrated that nitrosylsulfuric acid can be successfully used as a tandem nitrosating and oxidizing agent in the synthesis of 3,5-diarylisoxazoles from 1,2-diarylcyclopropanes. The reaction proceeds highly regioselectively in the case of symmetric diarylcyclopropanes. The mixtures of regioisomeric 3,5-diarylisoxazoles were obtained from non-symmetric 1,2-diarylcyclopropanes.
About the authors
O. B. Bondarenko
Department of Chemistry, M. V. Lomonosov Moscow State University
Author for correspondence.
Email: k527.5msu@gmail.com
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991
A. I. Komarov
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: k527.5msu@gmail.com
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991
G. L. Karetnikov
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: k527.5msu@gmail.com
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991
S. N. Nikolaeva
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: k527.5msu@gmail.com
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991
N. V. Zyk
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: k527.5msu@gmail.com
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991
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