High-energy 4(10)-2-fluoro-2,2-dinitroethyl and 4(10)-2,2-dinitropropyl derivatives of polynitrohexaazaisowurtzitanes

O. A. Luk′yanov; N. I. Shlykova; G. V. Pokhvisneva; T. V. Ternikova; K. A. Monogarov; D. B. Meerov; Yu. V. Nelyubina; P. V. Dorovatovskii; T. S. Kon′kova

doi:10.1007/s11172-019-2424-4

High-energy 4(10)-2-fluoro-2,2-dinitroethyl and 4(10)-2,2-dinitropropyl derivatives of polynitrohexaazaisowurtzitanes

Authors: Luk′yanov O.A.¹, Shlykova N.I.¹, Pokhvisneva G.V.¹, Ternikova T.V.¹, Monogarov K.A.², Meerov D.B.², Nelyubina Y.V.³, Dorovatovskii P.V.⁴, Kon′kova T.S.²
Affiliations:
1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
2. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences
3. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
4. Russian Research Centre “Kurchatov Institute,”
Issue: Vol 68, No 1 (2019)
Pages: 110-115
Section: Full Articles
URL: https://ogarev-online.ru/1066-5285/article/view/243285
DOI: https://doi.org/10.1007/s11172-019-2424-4
ID: 243285

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Abstract

Methods for the syntheses of a series of high-energy 4(10)-2-fluoro-2,2-dinitroethyl and 4(10)-2,2-dinitroethyl derivatives of polynitrohexaazaisowurtzitanes were developed. The enthalpy of formation, molecular crystalline density, sensitivity to mechanical impact, and thermal stability were experimentally determined for two compounds.