Synthesis of selenium-containing derivatives of para-bromopropyl-substituted phenols


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Abstract

The dynamics of changes in the composition of the reaction mixture during the reaction of Na2SeSO3 and bromopropyl-substituted phenol in 50% aqueous ethanol and under the conditions of decreasing EtOH concentration in the reaction medium was studied. Convenient methods for the synthesis of 3-(4-hydroxyaryl)propyl selenosulfates and the corresponding diselenides were proposed. Symmetrical and unsymmetrical selenides (derivatives of alkylated phenols and pyrocatechol) were synthesized.

About the authors

S. V. Kholshin

Novosibirsk State Pedagogical University

Author for correspondence.
Email: s.kholshin@gmail.com
Russian Federation, 28 ul. Vilyuiskaya, Novosibirsk, 630126

S. E. Yagunov

Novosibirsk State Pedagogical University

Email: s.kholshin@gmail.com
Russian Federation, 28 ul. Vilyuiskaya, Novosibirsk, 630126

N. V. Kandalintseva

Novosibirsk State Pedagogical University; Novosibirsk Research Institute of Antioxidants

Email: s.kholshin@gmail.com
Russian Federation, 28 ul. Vilyuiskaya, Novosibirsk, 630126; 54a ul. Krasnyi Prospekt, Novosibirsk, 630091

A. E. Prosenko

Novosibirsk State Pedagogical University; Novosibirsk Research Institute of Antioxidants

Email: s.kholshin@gmail.com
Russian Federation, 28 ul. Vilyuiskaya, Novosibirsk, 630126; 54a ul. Krasnyi Prospekt, Novosibirsk, 630091

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