Email this article Coordination polymers based on zinc(ii) and manganese(ii) with 1,4-cyclohexanedicarboxylic acid
- Authors: Demakov P.A.1,2, Sapchenko S.A.1,2, Samsonenko D.G.1,2, Dybtsev D.N.1,2, Fedin V.P.1,2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
- Novosibirsk State University
- Issue: Vol 67, No 3 (2018)
- Pages: 490-496
- Section: Full Articles
- URL: https://ogarev-online.ru/1066-5285/article/view/242321
- DOI: https://doi.org/10.1007/s11172-018-2098-3
- ID: 242321
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Abstract
Three new metal-organic coordination polymers were obtained namely, [Mn3(chdc)3-(NMP)2(DMF)2] (1, chdc2– is trans-1,4-cyclohexanedicarboxylate, NMP is N-methylpyrrolidone, DMF is N,N-dimethylformamide), [Zn3(chdc)3(NMP)2]•2NMP (2), and [Zn3(chdc)3(ur)-(DMF)0.5]•DMF (3, ur is the urotropine). The crystal structures of polymers 1, 2, and 3 were determined by single-crystal X-ray crystallography. All three compounds were found to contain a trinuclear secondary building unit {M3(OOC)6}. Coordination polymers 1 and 2 have a layered structure, while polymer 3 has a three-dimensional coordination framework with isolated pores formed due to the presence of urotropine bridging molecules. Compounds 1 and 3 were characterized by IR spectroscopy, thermogravimetric and elemental analysis data, powder X-ray diffraction. Compound 3 was also characterized by UV-Vis diffuse reflectance spectrum.
About the authors
P. A. Demakov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Author for correspondence.
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentґeva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
S. A. Sapchenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentґeva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
D. G. Samsonenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentґeva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
D. N. Dybtsev
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentґeva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
V. P. Fedin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentґeva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
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