Hydrophilic functional copolymers of 1-vinyl-1,2,4-triazole with vinylsulfonic acid sodium salt


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Abstract

The free-radical copolymerization of 1-vinyl-1,2,4-triazole with vinylsulfonic acid sodium salt was conducted. New thermally stable functional water-soluble copolymers of various composition were synthesized. The structure and properties of the obtained copolymers were confirmed by IR, 1H NMR spectroscopy, and thermogravimetric methods. It was found that 1-vinyl-1,2,4-triazole has higher reactivity than sodium vinylsulfonate. TGA and DSC show that the produced copolymers are stable when heated to 260 °C.

About the authors

A. S. Pozdnyakov

A. E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch, Russian Academy of Sciences

Author for correspondence.
Email: pozdnyakov@irioch.irk.ru
Russian Federation, 1 ul. Favorskogo, Irkutsk, 664033

E. A. Sekretarev

A. E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch, Russian Academy of Sciences

Email: pozdnyakov@irioch.irk.ru
Russian Federation, 1 ul. Favorskogo, Irkutsk, 664033

A. I. Emel’yanov

A. E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch, Russian Academy of Sciences

Email: pozdnyakov@irioch.irk.ru
Russian Federation, 1 ul. Favorskogo, Irkutsk, 664033

G. F. Prozorova

A. E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch, Russian Academy of Sciences

Email: pozdnyakov@irioch.irk.ru
Russian Federation, 1 ul. Favorskogo, Irkutsk, 664033

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