Synthesis and piezoelectric properties of N-phthaloylglutamic acid derivatives
- Authors: Ustinova V.O.1, Vigorov A.Y.1, Gruzdev D.A.1, Nuraeva A.S.2, Nizova I.A.1, Chulakov E.N.1, Sadretdinova L.S.1, Slepukhin P.A.1,3, Zelenovsky P.S.2, Shur V.Y.2, Krasnov V.P.1
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Affiliations:
- I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
- Institute of Natural Sciences and Mathematics, Ural Federal University
- Institute of Chemical Engineering, Ural Federal University
- Issue: Vol 66, No 8 (2017)
- Pages: 1439-1445
- Section: Full Articles
- URL: https://ogarev-online.ru/1066-5285/article/view/241084
- DOI: https://doi.org/10.1007/s11172-017-1905-6
- ID: 241084
Cite item
Abstract
The (S,S)- and (R,R)-enantiomers of dimethyl 2,4-diphthalimidoglutarate were synthesized by nucleophilic substitution of bromine in dimethyl (2S,4RS)-4-bromo-N-phthaloyl-glutamate upon treatment with potassium phthalimide, followed by separation. The crystal structure of the obtained compounds was studied by X-ray diffraction. Crystals of enantiomerically pure dimethyl 4-hydroxy- and 4-phthalimido-N-phthaloylglutamates were found to possess a noticeable piezoelectric activity.
About the authors
V. O. Ustinova
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Email: gruzdev-da@ios.uran.ru
Russian Federation, 22 ul. S. Kovalevskoi, Ekaterinburg, 620990
A. Yu. Vigorov
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Email: gruzdev-da@ios.uran.ru
Russian Federation, 22 ul. S. Kovalevskoi, Ekaterinburg, 620990
D. A. Gruzdev
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Author for correspondence.
Email: gruzdev-da@ios.uran.ru
Russian Federation, 22 ul. S. Kovalevskoi, Ekaterinburg, 620990
A. S. Nuraeva
Institute of Natural Sciences and Mathematics, Ural Federal University
Email: gruzdev-da@ios.uran.ru
Russian Federation, 19 ul. Mira, Ekaterinburg, 620002
I. A. Nizova
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Email: gruzdev-da@ios.uran.ru
Russian Federation, 22 ul. S. Kovalevskoi, Ekaterinburg, 620990
E. N. Chulakov
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Email: gruzdev-da@ios.uran.ru
Russian Federation, 22 ul. S. Kovalevskoi, Ekaterinburg, 620990
L. Sh. Sadretdinova
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Email: gruzdev-da@ios.uran.ru
Russian Federation, 22 ul. S. Kovalevskoi, Ekaterinburg, 620990
P. A. Slepukhin
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences; Institute of Chemical Engineering, Ural Federal University
Email: gruzdev-da@ios.uran.ru
Russian Federation, 22 ul. S. Kovalevskoi, Ekaterinburg, 620990; 19 ul. Mira, Ekaterinburg, 620002
P. S. Zelenovsky
Institute of Natural Sciences and Mathematics, Ural Federal University
Email: gruzdev-da@ios.uran.ru
Russian Federation, 19 ul. Mira, Ekaterinburg, 620002
V. Ya. Shur
Institute of Natural Sciences and Mathematics, Ural Federal University
Email: gruzdev-da@ios.uran.ru
Russian Federation, 19 ul. Mira, Ekaterinburg, 620002
V. P. Krasnov
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Email: gruzdev-da@ios.uran.ru
Russian Federation, 22 ul. S. Kovalevskoi, Ekaterinburg, 620990
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