Email this article Stereochemistry of chromium complexes with monosubstituted allenes
- Authors: Krivykh V.V.1, Taits E.S.1, Petrovskii P.V.1
-
Affiliations:
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Issue: Vol 66, No 7 (2017)
- Pages: 1202-1207
- Section: Full Articles
- URL: https://ogarev-online.ru/1066-5285/article/view/240919
- DOI: https://doi.org/10.1007/s11172-017-1873-x
- ID: 240919
Cite item
Open Access
Access granted
Subscription Access
Abstract
Previously unknown arenechromium dicarbonyl complexes with different allenes including functionally substituted ones were synthesized. The formed compounds represent a mixture of all three possible isomers and exhibit stereochemical nonrigidity. The isomerization process and stereochemical peculiarities of the complexes synthesized were studied using the 1H NMR method.
About the authors
V. V. Krivykh
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Author for correspondence.
Email: vkriv@ineos.ac.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
E. S. Taits
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: vkriv@ineos.ac.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
P. V. Petrovskii
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: vkriv@ineos.ac.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
Supplementary files
