Email this article Ferrocenylalkylation of 2-mercaptobenzoxazoles
- Authors: Osipova E.Y.1, Ivanova A.S.1, Rodionov A.N.1,2, Korlyukov A.A.1, Arkhipov D.E.1, Simenel A.A.1,3
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Affiliations:
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- State Environmental Agency “Mosekomonitoring”
- The National University of Science and Technology “MISiS”
- Issue: Vol 65, No 12 (2016)
- Pages: 2868-2872
- Section: Full Articles
- URL: https://ogarev-online.ru/1066-5285/article/view/239555
- DOI: https://doi.org/10.1007/s11172-016-1670-y
- ID: 239555
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Abstract
Regioselectivity of the HBF4-catalyzed ferrocenylalkylation of 2-mercaptobenzoxazole in two phase aqueous organic solvent mixture was studied. The reaction proceeds regioselectively at the heterocyclic nitrogen atom. Structures of the synthesized compounds were established by 2D NMR technique. Structure of 3-(1-ferrocenylbenzyl)benz[d]oxazol-2-thione was elucidated by X-ray diffraction.
About the authors
E. Yu. Osipova
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Author for correspondence.
Email: jdyotvet@yandex.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
A. S. Ivanova
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: jdyotvet@yandex.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
A. N. Rodionov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; State Environmental Agency “Mosekomonitoring”
Email: jdyotvet@yandex.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991; Build. 1, 2 Dal’niy per., Moscow, 115419
A. A. Korlyukov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: jdyotvet@yandex.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
D. E. Arkhipov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: jdyotvet@yandex.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
A. A. Simenel
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; The National University of Science and Technology “MISiS”
Email: jdyotvet@yandex.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991; 2 Leninsky prosp., Moscow, 119049
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