Oligomerization of higher olefins and alkylation of toluene catalyzed by 2-[hydroxy(diaryl)methyl]-8-hydroxyquinoline oxovanadium(v) complexes


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Abstract

New oxovanadium(V) complexes with 2-[hydroxy(diaryl)methyl]-8-hydroxyquinoline ligands were synthesized. These compounds were found to be efficient tandem catalysts of oligomerization of hex-1-ene and alkylation of toluene, which leads to the mixture of hexyl-, dihexyl-, and trihexyltoluenes with the conversion of the starting alkene more than 99%.

About the authors

N. A. Kolosov

Department of Chemistry, M. V. Lomonosov Moscow State University

Email: b.bulychev@highp.chem.msu.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991

V. A. Tuskaev

Department of Chemistry, M. V. Lomonosov Moscow State University; A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: b.bulychev@highp.chem.msu.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991; 28 ul. Vavilova, Moscow, 119991

S. Ch. Gagieva

Department of Chemistry, M. V. Lomonosov Moscow State University

Email: b.bulychev@highp.chem.msu.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991

O. V. Polyakova

Department of Chemistry, M. V. Lomonosov Moscow State University

Email: b.bulychev@highp.chem.msu.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991

A. I. Sizov

Department of Chemistry, M. V. Lomonosov Moscow State University

Email: b.bulychev@highp.chem.msu.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991

B. M. Bulychev

Department of Chemistry, M. V. Lomonosov Moscow State University

Author for correspondence.
Email: b.bulychev@highp.chem.msu.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991

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