Oligomerization of higher olefins and alkylation of toluene catalyzed by 2-[hydroxy(diaryl)methyl]-8-hydroxyquinoline oxovanadium(v) complexes

N. A. Kolosov; V. A. Tuskaev; S. Ch. Gagieva; O. V. Polyakova; A. I. Sizov; B. M. Bulychev

doi:10.1007/s11172-016-1648-9

Oligomerization of higher olefins and alkylation of toluene catalyzed by 2-[hydroxy(diaryl)methyl]-8-hydroxyquinoline oxovanadium(v) complexes

Authors: Kolosov N.A.¹, Tuskaev V.A.¹^,2, Gagieva S.C.¹, Polyakova O.V.¹, Sizov A.I.¹, Bulychev B.M.¹
Affiliations:
1. Department of Chemistry, M. V. Lomonosov Moscow State University
2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Issue: Vol 65, No 11 (2016)
Pages: 2757-2759
Section: Brief Communications
URL: https://ogarev-online.ru/1066-5285/article/view/239466
DOI: https://doi.org/10.1007/s11172-016-1648-9
ID: 239466

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Abstract

New oxovanadium(V) complexes with 2-[hydroxy(diaryl)methyl]-8-hydroxyquinoline ligands were synthesized. These compounds were found to be efficient tandem catalysts of oligomerization of hex-1-ene and alkylation of toluene, which leads to the mixture of hexyl-, dihexyl-, and trihexyltoluenes with the conversion of the starting alkene more than 99%.