Email this article Synthesis and crystal structure of An(VI) complexes with cyclobutanecarboxylic acid anions and 2,2′-bipyridine [An(VI) = U, Np, Pu]
- Authors: Charushnikova I.A.1, Grigor’ev M.S.1, Fedoseev A.M.1
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Affiliations:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Issue: Vol 59, No 6 (2017)
- Pages: 554-561
- Section: Article
- URL: https://ogarev-online.ru/1066-3622/article/view/224234
- DOI: https://doi.org/10.1134/S1066362217060029
- ID: 224234
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Abstract
New complexes of hexavalent U, Np, and Pu of the composition [UO2(bipy)(cbc)2] (I) and [AnO2(bipy)(cbc)2]·0.5(bipy) [An = Np (II) and Pu (III)] with cyclobutanecarboxylic acid anions C4H7COO– and 2,2′-bipyridine (bipy) were synthesized, and their structures were studied. The An atoms in I–III have the coordination surrounding in the form of distorted hexagonal bipyramids with the О atoms of AnO22+ cations in the apical positions. The equatorial plane of the bipyramids is constituted by the O atoms of two C4H7COO– anions and N atoms of bipy.
About the authors
I. A. Charushnikova
Frumkin Institute of Physical Chemistry and Electrochemistry
Author for correspondence.
Email: charushnikovai@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071
M. S. Grigor’ev
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: charushnikovai@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071
A. M. Fedoseev
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: charushnikovai@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071
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