Crystal structure of [Co(en)3][NpO4(OH)2]·5H2O (en = ethylenediamine, H2N(CH2)2NH2)


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Resumo

A Np(VII) compound with [Co(en)3]3+ cations, [Co(en)3][NpO4(OH)2]·5H2O (en = ethylenediamine), was synthesized and studied by single crystal X-ray diffraction. The structure consists of [NpO4(OH)2]3– anions and [Co(en)3]3+ cations forming electrically neutral layers, between which water molecules are arranged. A three-dimensional network of hydrogen bonds involving all the constituents of the structure is formed in the crystal. The effect of hydrogen bonding on the geometric characteristics of [NpO4(OH)2]3– anions is discussed.

Sobre autores

I. Charushnikova

Frumkin Institute of Physical Chemistry and Electrochemistry

Autor responsável pela correspondência
Email: charushnikovai@ipc.rssi.ru
Rússia, Leninskii pr. 31, korp. 4, Moscow, 119071

N. Krot

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: charushnikovai@ipc.rssi.ru
Rússia, Leninskii pr. 31, korp. 4, Moscow, 119071

M. Grigor’ev

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: charushnikovai@ipc.rssi.ru
Rússia, Leninskii pr. 31, korp. 4, Moscow, 119071

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