Determining the Parameters of Tetrahedral Splittings in the A1- and A2-Type States of Molecules with Spherical Symmetry (Td or Оh)


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Abstract

A method of analytical description of one of the most complex problems in the study of high symmetry quantum-mechanical objects, namely, tetrahedral splittings, is considered. Results are presented that allow tetrahedral splittings of the vibrational states of A1 and A2 symmetries for polyad N ≤ 4 to be determined in an analytical form.

About the authors

N. I. Raspopova

Institute of Physics and Technology of the National Research Tomsk Polytechnic University

Author for correspondence.
Email: raspopovani@tpu.ru
Russian Federation, Tomsk

E. A. Sklyarova

Institute of Physics and Technology of the National Research Tomsk Polytechnic University

Email: raspopovani@tpu.ru
Russian Federation, Tomsk

Yu. S. Aslapovskaya

Institute of Physics and Technology of the National Research Tomsk Polytechnic University

Email: raspopovani@tpu.ru
Russian Federation, Tomsk

S. I. Kuznetsov

Institute of Physics and Technology of the National Research Tomsk Polytechnic University

Email: raspopovani@tpu.ru
Russian Federation, Tomsk

K. Maul

Technische Universität Braunschweig

Email: raspopovani@tpu.ru
Germany, Braunschweig

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