Size Effect in Nanocomposites Based on Molecular Ferroelectric Diisopropylammonium Bromide

Resumo

We present the results of studies of the dielectric properties of nanocomposites based on Al₂O₃ oxide films with a pore size of 330 and 60 nm with particles of an organic ferroelectric diisopropylammonium bromide (C₆H₁₆BrN, DIPAB) introduced into the pores, aimed at determining the size dependences of phase transition parameters. A shift in the phase transition to low temperatures and diffusion of the transition are found, which become more significant for smaller pores. A broadening of the temperature hysteresis of the dielectric constant of nanocomposites during the phase transition was also observed. The decrease in the phase transition temperature in nanocomposites with DIPAB nanoparticles is consistent with theoretical models of the size effects on the structural phase transition.