Transferability of Crystal-Field Parameters for Rare-Earth Ions in Y2SiO5 Tested by Zeeman Spectroscopy


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Abstract

Zeeman spectroscopy is used to demonstrate that phenomenological crystal-field parameters determined for the two C1 point-group symmetry sites in Er3+:Y2SiO5 may be transferred to other ions. The two crystallographic six-and seven-coordinate substitutional sites may be distinguished by comparing the spectra with crystal-field calculations.

About the authors

N. L. Jobbitt

School of Physical and Chemical Sciences, University of Canterbury; The Dodd-Walls Centre for Photonic and Quantum Technologies

Email: mike.reid@canterbury.ac.nz
New Zealand, Christchurch, PB 4800; Dunedin

S. J. Patchett

School of Physical and Chemical Sciences, University of Canterbury; The Dodd-Walls Centre for Photonic and Quantum Technologies

Email: mike.reid@canterbury.ac.nz
New Zealand, Christchurch, PB 4800; Dunedin

Y. Alizadeh

School of Physical and Chemical Sciences, University of Canterbury; The Dodd-Walls Centre for Photonic and Quantum Technologies

Email: mike.reid@canterbury.ac.nz
New Zealand, Christchurch, PB 4800; Dunedin

M. F. Reid

School of Physical and Chemical Sciences, University of Canterbury; The Dodd-Walls Centre for Photonic and Quantum Technologies

Author for correspondence.
Email: mike.reid@canterbury.ac.nz
New Zealand, Christchurch, PB 4800; Dunedin

J.-P. R. Wells

School of Physical and Chemical Sciences, University of Canterbury; The Dodd-Walls Centre for Photonic and Quantum Technologies

Email: mike.reid@canterbury.ac.nz
New Zealand, Christchurch, PB 4800; Dunedin

S. P. Horvath

School of Physical and Chemical Sciences, University of Canterbury; Department of Physics, University of Otago

Email: mike.reid@canterbury.ac.nz
New Zealand, Christchurch, PB 4800; Dunedin

J. J. Longdell

Department of Physics, University of Otago; Chimie ParisTech, PSL University, CNRS, Institut de Recherche de Chimie Paris

Email: mike.reid@canterbury.ac.nz
New Zealand, Dunedin; Paris

A. Ferrier

Chimie ParisTech, PSL University, CNRS, Institut de Recherche de Chimie Paris; Faculté des Sciences et Ingénierie, Sorbonne Université

Email: mike.reid@canterbury.ac.nz
France, Paris; Paris

P. Goldner

Faculté des Sciences et Ingénierie, Sorbonne Université

Email: mike.reid@canterbury.ac.nz
France, Paris

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