Mechanism of the Yb2+ → Yb3+ valence transition in ytterbium nanofilms upon chemisorption of CO and O2 molecules on their surface

Abstract

The dependences of the work function of ytterbium nanofilms with a thickness ranging from 1 to 32 monolayers on the amount of CO or O₂ molecules chemisorbed on their surface have been investigated experimentally. It has been found that these dependences have a pronounced nonmonotonic character. The mechanism of the Yb²⁺ → Yb³⁺ valence transition, which occurs upon the chemisorption of CO or O₂ molecules on the surface of ytterbium nanofilms, has been developed using the results of this study together with the previously obtained data.