Behavior of noble metals upon fractional crystallization of copper-rich sulfide melts
- Авторы: Distler V.V.1, Sinyakova E.F.2, Kosyakov V.I.3
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Учреждения:
- Institute of Geology of Ore Deposits, Petrography, Mineralogy, and Geochemistry
- Sobolev Institute of Geology and Mineralogy, Siberian Branch
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Выпуск: Том 469, № 2 (2016)
- Страницы: 811-814
- Раздел: Geochemistry
- URL: https://ogarev-online.ru/1028-334X/article/view/188721
- DOI: https://doi.org/10.1134/S1028334X1608002X
- ID: 188721
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Аннотация
Joint behavior of Pt, Pd, Au, As, Bi, Te, and Sn upon fractional crystallization was studied in a melt of cubanite composition with the following admixtures (mol %): Fe, 33.20; Cu, 16.55; S, 50.03; Pt, 0.03; Pd, 0.02; Au, 0.02; As, 0.02; Bi, 0.03; Te, 0.02; Sn, 0.08. The crystallized sample consisted of three zones: (I) a pyrrhotite solid solution POSS; (II) an isocubanite ICB; (III) a multiphase mixture. The behavior of admixtures was studied in the first and second zones. It was shown that pyrrhotite did not contain admixtures of noble metals and accessory elements, whereas Sn was dissolved in cubanite. Other admixtures occurred in the second zone as multiphase inclusions. PdBiхTe1–х, PtBiS3–δ, CuPtBiS3, Bi2S3–х, Au, Pt(As,S)2, (Pt,Pd)S, (Pt,Pd)(Bi,Te)2–x, and PdBi2 were the most abundant phases.
Об авторах
V. Distler
Institute of Geology of Ore Deposits, Petrography, Mineralogy, and Geochemistry
Автор, ответственный за переписку.
Email: distler@igem.ru
Россия, Staromonetny per. 35, Moscow, 119017
E. Sinyakova
Sobolev Institute of Geology and Mineralogy, Siberian Branch
Email: distler@igem.ru
Россия, Akad. Koptyuga pr. 3, Novosibirsk, 630090
V. Kosyakov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: distler@igem.ru
Россия, Akad. Lavrentieva 3, Novosibirsk, 630090
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