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Vol 483, No 1 (2018)

Geology

Age and Boundaries of the Olekma Magmatic Belt of the Selenga–Stanovoi Superterrane (Central Asian Mobile Belt)

Kovach V.P., Kotov A.B., Larin A.M., Sal’nikova E.B., Velikoslavinskii S.D., Yakovleva S.Z., Plotkina Y.V.

Abstract

The Olekma magmatic belt of the Selenga–Stanovoi Superterrane within the Central Asian mobile belt is traced for a distance of more than 700 km. As a result of U–Pb geochronological studies, it was established that granitoids of the Olekma Complex have the Paleozoic age (355 ± 2 and 358 ± 2 Ma) in the eastern and central part of the belt, whereas consolidation of granitoids with a similar composition in the western segment occurred in the Early Mesozoic (237 ± 1 Ma). The formation of Mesozoic granitoids of the Olekma Complex occurred under the conditions of lithospheric extension, whereas Late Paleozoic granitoids were most likely formed during the collision of the Selenga–Stanovoi Superterrane and structures of the Baikal mountain area.

Doklady Earth Sciences. 2018;483(1):1375-1379
pages 1375-1379 views

The Hydrodynamic Regime of Groundwaters in Coal and Oil-Shale Mining Leases

Mokhov A.V.

Abstract

The data on the underworking of water objects and piezometric surveys have allowed scientists to reveal a correlation between hydrodynamic conditions in groundwaters and the stressed and strained state of rock masses at the sites of underground mining of coal and oil-shale deposits. The hydraulic fracturing of the downward filtration current within the layers of clay rocks and upon their contact with sand- and limestone layers was found, along with a discontinuous distribution of hydrostatic pressure in the section of the water-conducting subsidence cracks resulting in groundwater accumulation on clay layers.

Doklady Earth Sciences. 2018;483(1):1380-1383
pages 1380-1383 views

First Results of Dating Detrital Zircons from Late Precambrian Coarse Clastic Sequences of Ulutau Massif, Central Kazakhstan

Kanygina N.A., Letnikova E.F., Degtyarev K.E., Tretyakov A.A., Zhimulev F.I., Proshenkin A.I.

Abstract

U–Pb geochronological studies of detrital zircons from the Late Precambrian coarse sequence of the Ulutau massif are studied. The concordant ages of detrital zircons from the Satan Fm. composing the lower part of the Ulutau Series are formed by Neoproterozoic (740–888 Ma) and Paleoproterozoic (1989–2600 Ma) populations with the main peaks at 810 and 840 Ma, while less expressed peaks at 2017, 2036, and 2073 Ma. The concordant ages of detrital zircons from the upper part of the studied series, represented by coarse terrigenous rocks of glacial genesis (Baikonur Fm.), are predominantly within the intervals of 650–708, 721–729, and 754–889 Ma with peaks at 674, 721, 763, 772, 791, 821, and 840 Ma. The data obtained indicate that the lower age limit of coarse rocks from the Ulutau Series is about 670 Ma; these rocks formed mainly due to erosion of Neoproterozoic igneous complexes of the basement, which are widespread in the adjacent Maityube zone, with an insignificant role played by older basement rocks of the Ulutau massif.

Doklady Earth Sciences. 2018;483(1):1384-1387
pages 1384-1387 views

New Data on the Tectonics of Franz Joseph Land (Archipelago and Shelf, Northern Segment of the Continental Margin of the Barents Sea)

Shipilov E.V., Shkarubo S.I., Matishov G.G., Mityaev M.V., Kozlova O.V.

Abstract

The current block structure of the archipelago and the surrounding shelf are associated with the tectonic framework of the diagonal system of faults. The northeast-striking faults are in correlation with the series of normal faults in the flank of the Eastern Barents megabasin at the initial, rift-induced stage of the formation in the Middle–Late Paleozoic. The northwest-striking faults were formed in the Jurassic–Cretaceous time, during the tectonic–magmatic stage related to the dominating rift-induced spreading processes in the Arctic affected by the plume. In the archipelago and adjacent shelf, these faults control the zone of transtension about 400 km wide, which appears to be an alteration of grabens and horsts combined with traces of echelon dikes. Therefore, the crossing structural plan of the arched-block rise was formed. This structure was activated in the neotectonics epoch and modified by exaration and erosion.

Doklady Earth Sciences. 2018;483(1):1388-1393
pages 1388-1393 views

The Paleomagnetic Pole of the Siberian Paleocontinent at the Late Ediacaran Stage of Evolution of the Active Continental Margin (South Yenisei Ridge)

Kadilnikov P.I., Vernikovskaya A.E., Mikhaltsov N.E., Vernikovsky V.A., Matushkin N.Y.

Abstract

The results of the first paleomagnetic study of a late Neoproterozoic magmatic complex on the Siberian paleocontinent (Siberia) using U–Pb geochronological data are presented. The igneous rocks of the Zimoveyniy massif (block) of the South Yenisei Ridge formed in an active continental margin setting and recorded the initial thermoremanent magnetization. Our calculations let us determine with reasonable certitude that in the late Ediacaran Siberia was located in the subequatorial latitudes.

Doklady Earth Sciences. 2018;483(1):1394-1398
pages 1394-1398 views

Modern and Paleotravertines from Gorny Altai: Indicative Features

Kokh S.N., Sokol E.V., Deev E.V., Ryapolova Y.M., Rusanov G.G.

Abstract

This work reports new geochemical and stable isotope data on the Late Quaternary travertines of the southeastern Gorny Altai. The travertines are composed of Mg-calcite and Sr-aragonite, which cement the Sartan moraines and Holocene colluvium. The isotope characteristics of CaCO313C = –4.1…+0.9‰ and δ18O = –13.8…–13.9‰, VPDB) indicate a mixed carbon source, while the oxygen source is sedimentation water of the early diagenetic stage. The formation of travertines is controlled by the following factors: faults, underlying deformed carbonate rocks, dissected relief overlain by colluvium and/or moraine sediments, and the ascending fluid flow.

Doklady Earth Sciences. 2018;483(1):1399-1404
pages 1399-1404 views

Significance of the Sedimentary Water Integrity of the Neo-Pleistocene Aquifer System in the Northern Near-Caspian Region for the Development of the Caspian Sedimentary Basin

Golovanova O.V.

Abstract

This paper presents a new model of the distinct formation of groundwater of the aquifer system of the Northern Near-Caspian Region. The absence of sedimentary water displacement in plane is shown. An increase in mineralization and a wide range of characteristics of the composition and properties of rocks and waters are explained by processes of the mass-exchange in the water-rock system under conditions of low groundwater flow. The complex of the factors and conditions responsible for the integrity or displacement of sedimentary waters is determined, and it is suggested that it should be used to study the current and ancient sedimentary basins.

Doklady Earth Sciences. 2018;483(1):1405-1409
pages 1405-1409 views

Principle of Formation of the Earth’s Crust under Natural Stress Conditions

Zubkov A.V.

Abstract

This article formulates the experimentally substantiated physical principle that the natural stress condition of the Earth’s crust is formed due to the superposition of stress fields, which is caused by the gravitational forces of the Earth and by tectonic and astrophysical forces that are produced by physical processes in space. The natural stress field is represented by the stress tensor regulatory components: \(\sigma _{z}^{{\text{N}}}\) = \( - \gamma H + {{\sigma }_{{zT}}} + {{\sigma }_{{z{\text{AF}}}}}\), \(\sigma _{x}^{{\text{N}}}\) = \( - \lambda \gamma H + {{\sigma }_{{xT}}} + {{\sigma }_{{x{\text{AF}}}}}\), \(\sigma _{y}^{{\text{N}}}\) = \( - \lambda \gamma H + {{\sigma }_{{yT}}} + {{\sigma }_{{y{\text{AF}}}}}\).

Doklady Earth Sciences. 2018;483(1):1410-1412
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Peculiarities of Hydrocarbon Generation at Great Depths in the Crust

Kerimov V.Y., Mustaev R.N., Osipov A.V.

Abstract

This article describes the peculiarities of hydrocarbon generation at great depths in the Earth’s crust. It is shown that all the conditions necessary for generation of oil and gas are kept at great depths in the crust in the zones of high pressures and temperatures. However, generation of hydrocarbons in such settings significantly differs from the processes of oil and gas formation at shallow depths. A complex system of mutual thermobaric factors and distribution of the oil and gas potential at great depths was revealed: the start of generation and the phase distribution of hydrocarbons in the section are largely affected by settling of abnormally high pore pressure, as well as by paleotemperatures that could differ considerably from the present-day ones depending on the age of deposits. It is shown that different thicknesses of catagenetic zones are related to the kinetic rate of oil and gas generation, which depends on the type of kerogen, the gradient of temperature change, pressure, lithology, and hydrogeological conditions of the host rocks, the sedimentation rate, and other factors.

Doklady Earth Sciences. 2018;483(1):1413-1417
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The First Quantitative Evaluation Data on Vendian Metamorphism in the Eastern Part of the Bashkir Meganticlinorium

Kovalev S.G., Puchkov V.N., Kovalev S.S., Vysotskii S.I.

Abstract

This paper reports the data on the P–T parameters of the Vendian metamorphism within the eastern wing of the Bashkir Meganticlinorium. Regular near-EW variations in the P–T parameters are due to the fact that the Late Vendian Southern Urals developed under compression resulting from orogenic movements in the Timanides fold region. The stress metamorphism is specified by the “near-fault” nature, when the metamorphosed rock zones alternate with unaltered deposits.

Doklady Earth Sciences. 2018;483(1):1418-1422
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Structure and the Age of Conglomerates of Mount Southern Demerdzhi Based on the First U/Pb Dating of Detrital Zircons (Upper Jurassic, Crimean Mountains)

Rud’ko S.V., Kuznetsov N.B., Romanyuk T.V., Belousova E.A.

Abstract

U/Pb-isotope dating of detrital zircons from conglomerates of the reference section of the Demerdzhi Formation on the western slope of Mount Southern Demerdzhi was carried out. A cluster of the five youngest, reliably dated zircons with an average age of 154.1 ± 0.73 Ma was revealed, which indicates that the formation of conglomerates overlying the studied layer began to form not earlier than in the Late Kimmeridgian. The dating obtained forces us to reconsider the age of the Demerdzhi Formation, which was previously specified as Oxfordian–Early Kimmeridgian. New data on the age of thecoarse-grained sedimentary rocks of the Crimean Mountains advance concepts about Late Jurassic Cimmerian tectonic activity on the northern Tethys margin.

Doklady Earth Sciences. 2018;483(1):1423-1426
pages 1423-1426 views

Geochemistry

Experimental Modeling of C0-Forming Processes Involving Cohenite and CO2-Fluid in a Silicate Mantle

Bataleva Y.V., Palyanov Y.N., Borzdov Y.M., Bayukov O.A., Sobolev N.V.

Abstract

Experimental studies were performed in the Fe3C–SiO2–(Mg,Ca)CO3 system (6.3 GPа, 1100–1500°C, 20–40 h). It is established that the carbide–oxide–carbonate interaction leads to the formation of ferrosilite, fayalite, graphite, and cohenite (1100 and 1200°С), as well as a Fe–C melt (1300°С). It is determined that the main processes in the system are decarbonation, redox-reactions of cohenite and a CO2-fluid, extraction of carbon from carbide, and crystallization of metastable graphite (± diamond growth), as well as the formation of ferriferous silicates. The interaction studied can be considered as a simplified model of the processes that occur during the subduction of oxidized crustal material to reduced mantle rocks.

Doklady Earth Sciences. 2018;483(1):1427-1430
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Pseudomorphic Rhythmically Banded and Oscillatory Tetrahedrite–Tennantite Aggregates in the Darasun Gold Deposit (Eastern Transbaikalia, Russia): A Result of Coupled Dissolution–Reprecipitation Reactions

Vikent’eva O.V., Prokofiev V.Y., Lyubimtseva N.G., Bortnikov N.S., Borisovsky S.E.

Abstract

The rhythmically banded aggregates of Fe–tennantite with oscillatory zoning resulting from simultaneous variations in the concentrations of Sb and As and Zn and Fe were registered in the Darasun gold deposit (Eastern Transbaikalia). These aggregates were formed upon pseudomorphic replacement of early Zn–tetrahedrite. This process was initiated by the dissolution of Zn–tetrahedrite with the formation of an aggregate of galena, bournonite, and late tetrahedrite–tennantite. It is shown that rhythmically banded aggregates with an oscillatory zoning were formed as a result of coupled dissolution–reprecipitation reactions under the conditions that are far from the mineral–fluid chemical equilibrium and variations in the fluid composition controlled by kinetic factors.

Doklady Earth Sciences. 2018;483(1):1431-1436
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Chemical and Os-Isotopic Composition of Ru–Os Sulfides from the Verkh-Neivinsky Dunite-Harzburgite Massif (Middle Urals, Russia)

Malitch K.N., Badanina I.Y., Belousova E.A., Murzin V.V.

Abstract

This study presents new chemical and isotope data for Ru–Os sulfides and coexisting platinum-group minerals (PGMs) within primary assemblage derived from the Verkh-Neivinsky dunite-harzburgite massif. PGMs were studied using electron microprobe analysis, laser ablation and multiple collector-inductively coupled plasma-mass spectrometry. The obtained results are consistent with: (i) high-temperature formation of Ru–Os sulfides and coexisting Os-bearing alloys, (ii) presence of two contrasting sources in the ore formation (i.e., subchondritic and suprachondritic), (iii) resemblance of the initial Os-isotope composition in coexisting laurite and Os-bearing alloy, (iv) significant Os-isotope variations in individual PGMs from the primary assemblage, and (v) potential of using model 187Os/188Os ages of PGMs for geodynamic paleoreconstructions.

Doklady Earth Sciences. 2018;483(1):1437-1441
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Palladium (II) Biosorption by the Cell Wall of Penicillium canescens

Pavlova L.M., Nekrasov E.V., Radomskaya V.I., Shumilova L.P., Borodina N.A., Sorokin A.P.

Abstract

Based on the experimental research on determining the role of functional groups of the cell wall in the microfungus Penicillium canescens in the process of Pd(II) biogenic precipitation, it is revealed that hydroxyl and, to a lesser degree, amine groups participate in the sorption process in a weakly acidic medium (рН ~ 6), which is the most typical for natural conditions. The role of carboxyl groups under these conditions is not clear. The results obtained are of certain interest for understanding the mechanisms of platinoid mineral formation in organogenic sequences.

Doklady Earth Sciences. 2018;483(1):1442-1444
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Late Permian Intraplate Magmatism of the Baikal–Muya Belt: U–Pb Geochronology and Nd-Isotope Data

Rytsk E.Y., Salnikova E.B., Velikoslavinskii S.D., Bogomolov E.S., Andreev A.A., Kovach V.P., Anisimova I.V., Fedoseenko A.M.

Abstract

This paper presents the results of U–Pb isotope–geochronological study on zircons from subalkali gabbros and granodiorites of the Dogaldyn intrusive massif located in the Karalon–Mamakan zone of the Baikal–Muya belt. The ages of 254 ± 2 and 256 ± 1 Ma yielded for rocks of the two main intrusion phases do not differ significantly from each other and correspond to the Late Permian period. The Nd-isotope and geochemical data indicate the relationship between the primary melts of intraplate rocks from the Dogaldyn Massif and various sources, including plume–mantle and ancient crustal ones. The manifestations of Late Permian intraplate magmatic activity in the Baikal–Muya belt could have been induced by the Iberian superplume framed by the Siberian trap province.

Doklady Earth Sciences. 2018;483(1):1445-1450
pages 1445-1450 views

Formation of Water-Bearing Defects in Olivine in the Presence of Water–Hydrocarbon Fluid at 6.3 GPa and 1200°C

Sokol A.G., Kupriyanov I.N., Tomilenko A.A., Bul’bak T.A., Palyanov Y.N., Sobolev N.V.

Abstract

The main trends of water dissolution in Fe-bearing olivine have been investigated in the olivine–H2O–hydrocarbon fluid system in experiments at a pressure of 6.3 GPa, a temperature of 1200°C, and hydrogen fugacity ( fH2) buffered by the Mo–MoO2 equilibrium. The content and contribution of ОH defects of different types in Fe-bearing olivines depend on the composition of reduced fluids in the system. As the fraction of hydrocarbons in the fluid increases, the H2O content in olivine crystals decreases from 900 to 160–180 ppm, while the ОН absorption peaks become lower at high frequencies and occupy a larger part of the infrared spectrum in the low-frequency region. According to the experimental results, even the deepest seated mantle olivines with OH defects were not equilibrated with a fluid rich in light alkanes or oxygenated hydrocarbons.

Doklady Earth Sciences. 2018;483(1):1451-1453
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Geochemical Evolution and Ore-Bearing Metasomatic Rocks of the Baga-Gazryn Multiphase Massif of Rare-Metal Li–F Granites (Mongolia)

Antipin V.S., Kuzmin M.I., Odgerel D., Kousch L.V., Perepelov A.B.

Abstract

This paper considers the geochemical evolution of igneous and metasomatic rocks in the Baga-Gazryn Massif on the basis of new precision analytical data. The Baga-Gazryn rocks are characterized by enrichment in F, which is concentrated in Li–F mica, topaz, and fluorite. Along with F, zwitters and microclinites are enriched in Li, Rb, Cs, and ore elements Sn, W, Zn. High-charge elements (Zr, Hf, Nb, Ta, and Ti) and also Th and U are not very different in the Baga-Gazryn granites of various phases and metasomatic rocks.

Doklady Earth Sciences. 2018;483(1):1468-1472
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Genesis of Diamond in Metal–Carbon and Metal–Sulfur–Carbon Melts: Evidence from Experimental Data

Zhimulev E.I., Chepurov A.I., Sobolev N.V.

Abstract

The experimental data on diamond growth in the Fe–Ni–S–C and Fe–S–C systems with a sulfur content of 5–14 wt % at 5.5 GPa and 1300–1350°C are reported. Colorless and light yellow diamond crystals with a weight of 0.1–0.8 ct were synthesized. It is shown in the Fe–S–C system that at 5.5. GPa diamond may crystallize in a very narrow temperature range, from 1300 to 1370°C. Based on comparative analysis of the experimental data and the results of the study of native iron inclusions in natural diamonds from kimberlite pipes, it is suggested that diamond genesis may be partly controlled by the pre-eutectic (by the concentration of sulfur in relation to metal) metal–sulfide melt.

Doklady Earth Sciences. 2018;483(1):1473-1474
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Geochemical Constraints for the Bulk Composition of the Moon

Kronrod E.V., Kronrod V.A., Kuskov O.L., Nefedyev Y.A.

Abstract

The bulk composition of the silicate Moon (crust + mantle, BSM) is determined on the basis of inversion of gravitational and seismic data. It is shown that the mantle refractory oxides form two different groups depending on the thermal state. By the bulk Al2O3 content of ~3.0–4.6 wt %, the cold BSM models span the range of Al2O3 content of the silicate Earth (Bulk Silicate Earth, BSE), whereas the hot BSM models are significantly enriched in the Al2O3 content of ~5.1–7.3 wt % (Al2O3 content of ~1.2–1.7 × BSE) relative to BSE. In contrast, apart from the distribution of temperature, both BSM models are characterized by almost constant values of bulk FeO contents (~12.2–13.2 wt %) and MG# values (80.0–81.5), which are strongly distinct from those for BSE (~8 wt % FeO and 89 MG#). The results show that, for the geophysically possible distribution of temperatures, the silicate fraction of the Moon is enriched in FeO and depleted in MgO relative to BSE.

Doklady Earth Sciences. 2018;483(1):1475-1479
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Subsea Permafrost Thawing as a Factor of Changes in the Elemental Composition

Ulyantsev A.S., Polyakova N.V., Bratskaya S.Y., Romankevich E.A.

Abstract

The differences in the concentration of elements between thawed and frozen sediments were shown in the samples from two boreholes from the coastal zone of the Laptev Sea (Buor-Khaya Bay). The thalassogenic nature of enrichment of thawed deposits with sodium, chlorine, and to a lesser degree sulfur and phosphorus was confirmed. The difference in the concentration of chlorine between thawed and frozen soils may reach two orders.

Doklady Earth Sciences. 2018;483(1):1480-1484
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Zoning of REE Mineralization of the Udzha Region, Republic of Sakha (Yakutia)

Erlich E.

Abstract

On the basis of combined analysis of data on a geological survey on a scale of 1 : 200 000 (1959–1960) and exploration works (1980–1990), it was found that the zones of higher radioactivity and related rich La–Ce ores are localized along linear faults 10–15 km long parallel to the axis of the Udzha Anticline. The HREE mineralization of the Y–Yb group is concentrated in sandstones and gravelstones of the Vendian Tomtor Formation, which unconformably overlap the Udzha Anticline on its wings. This indicates that the volatile flow has a deep (transmagmatic) origin rather than separation from magma. A carbonatite body with sulfide veinlets and dissemination is described with respect to a zone of high contents of La–Ce ores. The complex character of the Tomtor ores is explained by the juxtaposition of mineralization phases of various ages and composition: Nb and Sc–Th mineralization paragenetically related to the central ring structure of the intrusion and to the external rischorrite zone, respectively.

Doklady Earth Sciences. 2018;483(1):1485-1486
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Geophysics

Рarametric Phenomena in Seismoelectrics

Kamshilin A.N., Nikolaev A.V., Chebotareva I.Y.

Abstract

Parametric phenomena (amplification of vibrations and the appearance of combinational frequencies) emerging in rocks during seismoelectric transformations are studied experimentally under field conditions. The geological medium in which periodic seismic vibrations are excited attains the properties of the parametric electrical oscillation system. Under certain conditions, there is a possibility of emergence of parametric resonance owing to transformation of elastic energy to energy of alternating electrical field produced in the solid earth. It was also proven experimentally that the electrical response to elastic vibrations can appear not only as a result of seismoelectric effects of the second type, but also due to the existence of parametric seismoelectric effects of the first type.

Doklady Earth Sciences. 2018;483(1):1454-1457
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Geography

Relief and Correlative Deposits of the Late Pleistocene and Holocene in Glacial Valleys of Kilgan Mountain, Okhotsk–Kolyma Region

Glushkova O.J., Smirnov V.N.

Abstract

The glacial and slope morphosculpture and correlated deposits of the Late Pleistocene and Holocene in the northeastern part of the Kilgan Mountains (Okhotsk–Kolyma region) were studied. The general three-element structure of loose cover in the glacial valley of Engteri Creek was established: moraine occurs in the lower part; proluvial deposits, in the middle; and covering deluvial deposits, on top. The sequence of postglacial evolution of slope processes was revealed. In the Atlantic (7245–5895 years ago), proluvial flows were the most active: they reached far beyond the slopes and covered moraine. Later, in the Subboreal, surface erosion intensified. The sedimentation rates in Dzhul’etta Lake were calculated. The glacial peak revealed in bottom sediments falls into the period of 19 410–13 880 years ago, with the smallest sedimentation rate, 6.3 cm/1000 years, which is lower compared to the underlying and overlying layers by a factor of two to three.

Doklady Earth Sciences. 2018;483(1):1458-1462
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Indicators of the Pollution of Surface Waters of the Lake Baikal Watershed by Polycyclic Aromatic Hydrocarbons

Semenov M.Y., Snytko V.A., Marinaite I.I., Silaev A.V., Semenov Y.M.

Abstract

The content of polycyclic aromatic hydrocarbons (PAH), organic carbon (Corg), and mineral nitrogen (Nmin) in waters of Lake Baikal and its tributaries were analyzed. On the basis of these data, the indicators of the water composition, for Baikal Lake and its tributaries, were worked up for the first time. These indicators—the anthropogenic impact on the ecosystem (PAH/Corg) and the indicator of the capacity of the ecosystem to neutralize pollution (Nmin/Corg)—show a link between water pollution and the conditions of the watershed basin. It was established that (PAH/Corg) and (Nmin/Corg) can be used simultaneously as tracers to calculate the tributary input into organic matter of the lake. It was also revealed that Nmin/Corg is inversely proportional to the Corg concentration and directly proportional to N/C in the soil humus. On the basis of the indicators, the watershed areas and water area of the lake were distinguished. The areas are characterized by different levels of the pollution, self-purification capacity, and concentration of carbon in surface waters.

Doklady Earth Sciences. 2018;483(1):1463-1467
pages 1463-1467 views