Vol 475, No 2 (2017)

During the Late Devonian extinction, 70–82% of all marine species disappeared. The main causes of this mass extinction include tectonic activity, climate and sea-level fluctuations, volcanism, and the collision of the Earth with cosmic bodies (impact events). The major causes are considered to be volcanism accompanying formation of the Viluy traps and, probably, basaltic magmatism in the Southern Urals, alkaline magmatism within the East European platform, and volcanism in northern Iran and northern and southern China. Several large impact craters of Late Devonian age have been documented in different parts of the world. The available data indicate that this time period on the Earth was marked by two major sequences of events: terrestrial events that resulted in extensive volcanism and cosmic (or impact) events. They produced similar effects such as emissions of harmful chemical compounds and aerosols to cause greenhouse warming and the darkening of the atmosphere, which prevented photosynthesis and cause ocean stagnation and anoxia. This disrupted the food chain and reduced ecosystem productivity. As a result, all vital processes were disturbed and a large part of the marine biota became extinct.

Results of complex paleontological and geochemical analysis are reported for a new locality of the Upper Oligocene–Lower Miocene Kosh-Agach carbonaceous formation in the Dzhazator River valley. This find specifies the scales of lacustrine–marsh sedimentation at the end of the Paleogene and beginning of the Neogene, as well as the character and amplitude of post-Neogene neotectonic movements in the southeastern highest mountain part of Russian Altai. Systematic rejuvenation of the radiocarbon age of the sequences studied, which has been established for the first time in Altai, is related to influx of young carbon during the subsequent complex geological history. This fact is of great importance for deciphering the chronology of Pleistocene glacial–dammed lakes in the intermontane basins of Altai and Tuva, the erosion zone of which spanned exhumed Tertiary deposits.

The results of U/Pb dating of detrital zircons from sandstones of the Zigalga Formation, which is the base level of the Middle Yurmatu Group of the Bashkir uplift, southwestern Urals, are presented. The U/Pb ages of detrital zircons from sandstones of the Lower, Middle, and Upper Riphean are compared.

Geochronological studies of rocks from a bimodal high-alkali volcanic–plutonic complex collected in the area of Kharkhorin zone of the Early Mesozoic Mongolian–Transbaikalian igneous province (MTIP) are made. The age of alkali granites from Olziit sum is 211 ± 1 Ma (U–Pb ID-TIMS on zircon) to 209 ± 2 and 217 ± 4 Ma (⁴⁰Ar/³⁹Ar on alkali amphibole); the age of alkali granite-porphyries from the area of Sant sum is 206 ± 1 Ma (U–Pb ID-TIMS on zircon). These rock series formed syncronously to the analogous magmatism episode in the Northern Gobi and Western Transbaikalian rift zones of the MTIP. The similarity of the age and composition of igneous associations of the MTIP suggests a common mechanism of its formation related to the effect of a mantle plume on the continental lithosphere at the base of the entire igneous zone having a zonal structure.

Assuming stability of the Black Sea system and conservative behavior of sulfate in relation to salinity outside the bottom convective layer (BCL), the influence of shelf-modified Mediterranean water (SMMW) on the water column of the Black Sea below the core of the cold intermediate layer (CIL) was estimated on the basis of variations in the sulfur isotope composition of sulfate. As a result of construction of the model of mixing of three water masses, it was shown that the SMMW fraction in the area of hydrogen sulfide onset at a salinity of 20.8–20.9 was 5–7 times higher than the amount of water produced by mixing of the CIL and the BCL. The SMMW fraction decreased with depth rapidly and was only 10% at a depth of 1000 m. Significant supply of SMMW to the pycnocline area provided a high renewal rate of water, which prevented accumulation of ³²S-rich sulfate resulted from hydrogen sulfide oxidation.

Thermodynamic modeling of the SiO₂–TiO₂–Al₂O₃–Fe₂O₃–MnO–MgO–CaO–Na₂O–K₂O–P₂O₅–H₂O (STAFMMCNKPOH) system at 600°C, 5 kbar has been applied to investigate dissolution and re-precipitation of quartz. Comparing silica molality in the STAFMMCNKPOH and SiO₂–H₂O systems, there is seen to be no effect of mineral assemblage on quartz solubility. From quantitatively estimated water/rock ratio required to dissolve quartz completely, one can deduce that the segregation of quartz appears to be due to diffusive transport of silica in inner pore fluid rather than to advective transport (in fluid flow).

Data are presented on the equilibrium compositions of olivine and melts in the products of 101 experiments performed at 1300–1600°C, atmospheric pressure, and controlled oxygen fugacity by means of new equipment at the Vernadsky Institute. It was shown that the available models of the olivine–melt equilibrium describe with insufficient adequacy the natural systems at temperatures over 1400°C. The most adequate is the model by Ford et al. (1983). However, this model overestimates systematically the equilibrium temperature with underestimating by 20–40°C at 1450–1600°C. These data point to the need for developing a new, improved quantitative model of the olivine–melt equilibrium for high-temperature magnesian melts, as well as to the possibility of these studies on the basis of the equipment presented.

The first data on the Late Riphean age by U–Pb and Sm–Nd analysis (≥922 ± 14 and 686 ± 19 Ma, respectively) were obtained for rocks of the dunite–clinopyroxenite–gabbro complex of the Chistop massif in the Patinum-bearing Belt of the Urals. These data allow one to assume that the formation of the Ural paleoocean probably started immediately after the break-up of Rodinia.

The primary melt and fluid inclusions in regenerated zonal crystals of olivine and homogeneous phenocrysts of olivine from kimberlites of the Udachnaya-East pipe, were first studied by means of microthermometry, optic and scanning electron microscopy, electron and ion microprobe analysis (SIMS), inductively coupled plasma mass-spectrometry (ICP MSC), and Raman spectroscopy. It was established that olivine crystals were regenerated from silicate–carbonate melts at a temperature of ~1100°C.

The zones of the origin of seismic centers within highly seismic areas of the Pamirs and Tien Shan are established. The majority of catastrophic earthquakes coincide with them in this part of High Asia. Their establishment is based on the distribution of the most intensive epicenters and the maximal volumes of the seismic energy together with its calculation and forecasting of the possible manifestations of high seismicity. The investigation of the deep structure of these zones allows us to determine the connection of the seismicity with geophysical field anomalies and some factors of the deep and near surface lithosphere and crust structure, which influence the present-day geodynamics. The results of our research enable us to appreciate the level of the seismic danger in different parts of the region investigated.

Based on a complex study of the upper crust structure in the southern margin of Kochkor basin (Northern Tien Shan), including study of the structure of the Cenozoic sedimentary cover, the deep geoelectrical structure, the structural unconformities, and occurrences of recent deformations in the basement rocks, new geological–geophysical cross sections are constructed. The cross sections show both fault structures that penetrate the cover from the basement and flat interplate detachments with related fold-overthrust structures. The comparison of the cross sections has established the absence of common planes of fault extensions along the entire margin of the hollow, except for the zone where the margin and the hollow adjoin, which can be caused by the zones of dynamic influence of secondary faults, the zones of fracturing, and the zones of cataclasis of blockwise disintegrated granite massifs.

Wavy spatial variations in the contents of trace gases are identified using plane measurements of O₃ concentrations in the medium troposphere and the total content (TC) of NO₂ in the atmospheric column from flights above the Subpolar Urals in April 1984. The results of model calculations allow us to relate these variations to mesoscale atmospheric disturbances above the mountains, which are caused by the influence of dynamic relief on the leaked-in flow.

An integrated study of the loess–soil sequence in the coastal exposure near the settlement of Beglitsa (Rostov oblast) allowed us, for the first time, to reconstruct the landscape-climatic changes that occurred in the eastern Azov region over the course of the Late Pleistocene. In the south of the periglacial zone, considerable differences between intensity of the loess accumulation in the Early and Late Valdai Cryochrons were revealed. In the Early Valdai Epoch, which corresponds roughly to the end of Marine Isotope Stage (MIS) 5 and MIS 4, loess accumulation occurred after completion of development of the Mezin pedocomplex and before the beginning of the Bryansk stage of soil development, i.e., over more than 20 000 years. In the much shorter Late Valdai Cryochron MIS 2 (10 000–12 000 years), loess accumulation reached 5 m. The data evaluation shows that the loess accumulation rates in the Early Valdai Epoch (~0.07 mm/year) and the Late Valdai Epoch (~0.5 mm/year) differ from each other by an order of magnitude.

An algorithm for mapping the vulnerability of sea-coastal zones is described. Normalization of the distribution densities of the biotic groups to the annual average abundance for presenting these data in identical measurement units is offered. Sensitivity of biota to oil should be normalized to the maximum permissible concentrations for the species inhabiting the water column and to the maximum permissible thickness of the film that has contacted with the water surface. All parameters should be estimated by the metric scale. The proposed algorithm makes it possible to calculate the vulnerability of a sea-coastal zone to oil pollution caused by oil spills.

High variability in methane fluxes at the water–atmosphere boundary was found for the first time for the period 1990–2016 using expeditionary data. Variability from absorption to emission with values of more than 5 kg km^–2 day^–1 was found in the whole sea area and over time. Increased emission in the Sea of Okhotsk is associated with distribution areas of through and composite anomalous gas-geochemical gas fields migrating from lithospheric sources. The interannual methane discharge into the atmosphere has an oscillatory seismic dependent nature.

The paper discusses the results of an experiment conducted in the Sea of Japan in March 2016 on an acoustic track 194 km long in winter hydrological conditions. The most complex case of propagation of pseudorandom pulse signals from the shelf to deep water in the presence of gyre formation on the acoustic track. An analysis of the experimentally obtained pulse characteristics show that at all points, a maximum, in terms of amplitude, first arrival of acoustic energy is recorded. This is evidence that at a given depth horizon, pulses that have passed the shortest distance through a near-surface sound channel at small angles close to zero are received first. The calculation method of mean sound velocity on the track, based on the satellite data of surface temperature monitoring, is proposed. We expect that the results obtained with this method can be successfully used for the purposes of acoustic range finding and navigation.