Changes in the Structure and Properties of Fluorocarbon Coatings under Irradiation with Accelerated C60 Ions

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

The first results of combined deposition of coatings from a beam of accelerated C60 fullerene ions and fluoroplastic vapor (polymetrized tetrafluoroethylene, PTFE) are presented. The coatings were formed by condensation of thermally evaporated PTFE on a Si substrate in vacuum under irradiation with a C60 ion beam with an energy of 5 keV, passed through a mass spectrometer. The calculated ratio of C60 ions and molecular fragments condensing on the substrate (–CF2–CF2–) was chosen close to 1:1. The structure and chemical bonds have been studied by Raman scattering and X-ray photoelectron spectroscopy, according to which the coating contains about 8.6 at. % fluorine. The coating contains ~35% sp3 bonds, with a sp3/sp2 ratio of ~0.76, and the main part (up to 50%) of fluorine–carbon bonds is concentrated in the form of polymer chains –CF2–CF2–, which are located in a solid carbon matrix, that is, the coating structure is nanocomposite. Mechanical tests showed high hardness of the coating H~32 GPa with an H/E ratio of ~0.16 (E is Young's modulus). The coating is characterized by a high contact angle of wetting with distilled water (CA = 98°). Tribological tests showed a coefficient of friction close to 0.18, with low wear of less than 10–7 mm3/N m.

About the authors

V. E Pukha

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry RAS; Hydrogen Energy Center Ltd.

Author for correspondence.
Email: pve@icp.ac.ru
Chernogolovka, Russia; Chernogolovka, Russia

G. V Nechaev

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry RAS

Email: pve@icp.ac.ru
Chernogolovka, Russia

E. N Kabachkov

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry RAS; Osipyan Institute of Solid State Physics RAS

Email: pve@icp.ac.ru
Chernogolovka, Russia; Chernogolovka, Russia

I. N Lukina

Baikov Institute of Metallurgy and Materials Science RAS

Email: pve@icp.ac.ru
Moscow, Russia

E. I Drozdova

Baikov Institute of Metallurgy and Materials Science RAS

Email: pve@icp.ac.ru
Moscow, Russia

O. P Chernogorova

Baikov Institute of Metallurgy and Materials Science RAS

Email: pve@icp.ac.ru
Moscow, Russia

References

  1. Кудашев С.В. // Fluorine Notes. 2020. V. 3 (130). P. 2020. http://ru.notes.fluorinel.ru/public/2020/3_2020/article_2.html
  2. Puts G.J., Crouse P., Ameduri B.M. // Chem. Rev. 2019. V. 119. № 3. P. 1763. https://doi.org/10.1021/acs.chemrev.8b00458
  3. Piwowarczyk J., Jedrzejewski R., Moszyński D., Kwiatkowski K., Niemczyk A., Baranowska J. // Polymers. 2019. V. 11. № 10. P. 1629. https://doi.org/10.3390/polym11101629
  4. Ju Y., Ai L., Qi X., Li J., Song W. // Materials. 2023. V. 16. № 10. P. 3764. https://doi.org/10.3390/ma16103764
  5. Sharifahmadian O., Pakseresht A., Mirzaei S., Eliáš M., Galusek D. // Diam. Relat. Mater. 2023. V. 138. P. 110252. https://doi.org/10.1016/j.diamond.2023.110252
  6. Kim S.H., Kim M., Um M.S., Choi W.J., Lee J.H., Yang Y.S., Lee S.J. // Sci. Rep. 2019. V. 9. № 1. P. 10664. https://doi.org/10.1038/s41598-019-46993-0
  7. Grysenko K., Kolomzorov Y., Lyvyn P., Kondratenko O., Sopinsky M., Lebedyeva I., Niemczyk A., Baranowska J., Moszyński D., Villringer C., Schrader S. // Macromol. Mater. Eng. 2023. V. 308. № 6. P. 2200617. https://doi.org/10.1002/mame.202200617
  8. Gaber H., Busmann H.G., Hiss R., Hertel IV., Romberg H., Fink J., Bruder F., Brenn R. // J. Phys. Chem. 1993. V. 97. № 31. P. 8244. https://doi.org/10.1021/j100133a021
  9. Popok V.N., Barke I., Campbell E.E., Meiwes-Broer K.H. // Surf. Sci. Rep. 2011. V. 66. Iss. 10. P. 347. https://doi.org/10.1016/j.surfrep.2011.05.002
  10. Pukha V.E., Zubarev E.N., Drozdov A.N., Pugachov A.T., Jeong S.H., Nam S.C. // J. Phys. D. 2012. V. 45. Iss. 33. P. 335302. https://doi.org/10.1088/0022-3727/45/33/335302
  11. Penkov O.V., Pukha V.E., Zubarev E.N. et al. // Tribol. Int. 2013. V. 60. P. 127. https://doi.org/10.1016/j.triboint.2012.11.011
  12. Pukha V.E., Karbovskii V.L., Drozdov A.N., Pugachov A.T. // J. Phys. D. 2013. V. 46. Iss. 48. P. 485305. https://doi.org/10.1088/0022-3727/46/48/485305
  13. Penkov O.V., Pukha V.E., Starikova S.L., Khadem M., Starikov V.V., Maleev M.V., Kim D.E. // Biomaterials. 2016. V. 102. P. 130. https://doi.org/10.1016/j.biomaterials.2016.06.029
  14. Khadem M., Pukha V.E., Penkov O.V., Khodos I.I., Belmesov A.A., Nechaev G.V., Kabachkov E.N., Karaseev P.A., Kim D.E. // Surf. Coat. Technol. 2021. V. 424. P. 127670. https://doi.org/10.1016/j.surfcoat.2021.127670
  15. Wang J., Ma J., Huang W., Wang L., He H., Liu C. // Surf. Coat. Technol. 2017. V. 316. P. 22. https://doi.org/10.1016/j.surfcoat.2017.02.065
  16. Zhang L., Wang F., Qiang L., Gao K., Zhang B., Zhang J. // RSC Adv. 2015. V. 5. Iss. 13. P. 9635. https://doi.org/10.1039/C4RA14078H
  17. https://fluralit.ru/ftoroplast/fluralit-issledovanie
  18. Luff P.P., White M. // Vacuum. 1968. V. 18. № 8. P. 437. https://doi.org/10.1016/0042-207X(68)90336-9
  19. Grytsenko K.P. // Russ. J. Gen. Chem. 2009. V. 79. P. 642. https://doi.org/10.1134/S1070363209030463
  20. Малеев М.Б., Зубарев Е.Н., Пуха В.Е., Дроздов А.Н., Вус А.С. // Металлофизика и новейшие технологии. 2015. Т. 37. № 6. С. 777. http://dspace.nbuv.gov.ua/handle/123456789/112255
  21. Diaz J., Paolicelli G., Ferrer S., Comin F. // Phys. Rev. B. 1996. V. 54. № 11. P. 8064. https://doi.org/10.1103/PhysRevB.54.8064
  22. Wang J., Ma J., Huang W., Wang L., He H., Liu C. // Surf. Coat. Technol. 2017. V. 316. P. 22. https://doi.org/10.1016/j.surfcoat.2017.02.065
  23. Lin Y.H., Syue Y.C., Lin H.D., Chen U.S., Chang Y.S., Chen J.R., Shih H.C. // Appl. Surf. Sci. 2008. V. 255. Iss. 5. P. 2139. https://doi.org/10.1016/j.apsusc.2008.07.084
  24. Nakao S., Yukimura K., Nakano S., Ogiso H. // IEEE Trans. Plasma Sci. 2013. V. 41. № 8. P. 1819. https://doi.org/10.1109/TPS.2013.2256800
  25. Yumitori S. // J. Mater. Sci. 2000. V. 35. P. 139. https://doi.org/10.1023/A:1004761103919
  26. Pukha V.E., Glukhov A.A., Belmesov A.A., Kabachkov E.N., Khodos I.I., Khadem M., Kim D.-E., Karaseov P.A. // Vacuum. 2023. V. 218. P. 112643. https://doi.org/10.1016/j.vacuum.2023.112643
  27. Ferrari A.C., Robertson J. // Phys. Rev. B. 2000. V. 61. Iss. 20. P. 14095. https://doi.org/10.1103/PhysRevB.61.14095
  28. Ferrari A.C. // Surf. Coat. Technol. 2004. V. 180. P. 190. https://doi.org/10.31857/S1028096024060106, EDN: DUXGFU 10.1016/j.surfcoat.2003.10.146
  29. Mallet-Ladeira P., Puech P., Toulouse C., Cazayous M., Ratel-Ramond N., Weisbecker P., Monthoux M. // Carbon. 2014. V. 80. P. 629. https://doi.org/10.1016/j.carbon.2014.09.006
  30. Пуха В.Е., Бельмесов А.А., Кабачков Е.Н., Нечаев Г.В., Лукина И.Н., Дроздова Е.И., Черногорова О.П. // Поверхность. Рентген., синхротр. и нейтрон. исслед. № 6. 2024. С. 70. https://doi.org/10.31857/S1028096024060106, EDN: DUXGFU
  31. Fontaine J., Donnet C., Erdemir A. // Tribology of Diamond-Like Carbon Films: Fundamentals and Applications. Boston: Spinger, 2008. P. 139. https://doi.org/10.1007/978-0-387-49891-1_5
  32. Rajak D.K., Kumar A., Behera A., Menezes P.L. // Appl. Sci. 2021. V. 11. № 10. P. 4445. https://doi.org/10.3390/app11104445
  33. Wang J., Ma J., Huang W., Wang L., He H., Liu C. // Surf. Coat. Technol. 2017. V. 316. P. 22. https://doi.org/10.1016/j.surfcoat.2017.02.065
  34. Imai T., Hartgat T., Tanimoto T., Isono R., Iijima Y., Suda Y., Takikawa H., Kamiya M., Toki M., Hasegawa Y., Kaneko S., Kunitsugu S., Ito M. // Vacuum. 2019. V. 167. P. 536. https://doi.org/10.1016/j.vacuum.2018.07.009

Supplementary files

Supplementary Files
Action
1. JATS XML
Download

Copyright (c) 2025 Russian Academy of Sciences

Согласие на обработку персональных данных

 

Используя сайт https://journals.rcsi.science, я (далее – «Пользователь» или «Субъект персональных данных») даю согласие на обработку персональных данных на этом сайте (текст Согласия) и на обработку персональных данных с помощью сервиса «Яндекс.Метрика» (текст Согласия).