


卷 49, 编号 3 (2019)
- 年: 2019
- 文章: 14
- URL: https://ogarev-online.ru/0967-0912/issue/view/11235
Article
Modification of High-Manganese Steel Castings with Titanium Carbonitride
摘要
Modification of high-manganese steel castings in the mold by titanium carbonitride is investigated. First, the basic principles of alloying and modification of cast alloys are outlined, and the relevant literature is reviewed. That provides the basis for formulating the research goals. The practical significance of the research for casting enterprises is confirmed. Next, the materials employed are considered in detail: the batch components, the modifier, the materials used in the casting molds. Likewise, the experimental methods are described: in particular, the methods used in producing experimental castings and in determining the thermal conditions in the mold and the optimal heat treatment. In addition, the metallographic techniques employed are noted. The experimental results regarding the modification of the steel casting by fine titanium-carbonitride powder in the mold are presented. The influence of such modification on the performance of the high-manganese steel is considered, in terms of improved abrasive and impact–abrasive wear resistance. Metallographic data explain the basis for the improved performance of the high-manganese steel. The influence of the thermal conditions in the mold is considered: in particular, the influence of the rate of alloy cooling in the mold on the performance of the modified high-manganese steel. Finally, on the basis of the research findings, recommendations are made for improving the performance of cast high-manganese steel products. In addition, recommendations are made regarding the optimal consumption of titanium-carbonitride powder so as to obtain the required microstructure and properties of the high-manganese steel.



Convective Heat Transfer in Jet Interaction with a Boundary Surface
摘要
A method is proposed for calculating the convective heat transfer when a single circular jet interacts with a plane surface. The differences between this method and those currently existing are noted. The energy-dynamic potential of a flux and the energy-dynamic power of a flux are introduced. These concepts may be used to determine the rate of convective heat transfer at the gas–solid boundary. The differences between the proposed concepts and the existing concepts of the heat-flux density and heat flux are noted. The fundamental difference between the heat-flux density q and the energy-dynamic potential qe is as follows. The heat-flux density q for convective heat transfer is the heat transferred from a liquid to a solid surface (or conversely) in unit time through unit area of heat-transfer surface. Thus, q characterizes the rate of convective heat transfer at a phase boundary. By contrast, the energy-dynamic potential qe characterizes a property of the flux as a source or carrier of heat. Specifically, qe characterizes the unit power of the liquid flux. In calculating the heat transfer, the jet interacting with the surface may be divided into two parts: before interaction, a simple jet; after interaction, a fan-like flux. It is not entirely correct to calculate the convective heat transfer in jet heating on the basis of the Reynolds number calculated from the characteristics of the gas leaving the nozzle. Instead, characteristics of the fan-like flux must be used: specifically, the initial mean velocity Ufan of the fan-like flux; and the distance from the critical point of the jet (the point of intersection of the jet’s vertical axis and the surface) to the current radius downstream. To assess the change in the basic characteristics of the free jets with different distances from the nozzle outlet to the boundary surface, we present expressions for the expansion coefficient of the jet; the injection coefficient of the jet; the velocity coefficient for any cross section of the jet (including or excluding the nozzle’s outlet cross section); and the ratio of the Reynolds numbers. Our findings confirm the need to calculate the heat transfer on the basis of the characteristics of the fan-like flux.



Reduction of Tungsten from Its Oxide in Surfacing by Means of Powder-Core Wire
摘要
The influence of introducing tungsten and tungsten concentrate in powder-core wire on the structure, microhardness of the structural components, hardness, and wear of the applied metal layer is studied. For surfacing, tungsten-bearing powder wire (types H and E in the IIW classification) is produced in the laboratory. The fillers employed are KR-1 silicon powder (State Standard GOST 2169–69); MR-0 manganese powder (State Standard GOST 6008–82); PKhA-1M chromium powder (Technical Specifications TU 14-1-1474–75); VEL-1 vanadium (Technical Specifications TU 48-0533–71); PNK-1L5 nickel (State Standard GOST 9722–97); PAP-1 aluminum (State Standard GOST 5494–95); PVT tungsten (Technical Specifications TU 48-19-72–92); and PZhV-1 iron powder (State Standard GOST 0489–96). In some wire, tungsten powder is replaced by KSh-4 tungsten concentrate (State Standard GOST 213–83), produced by OAO GK AIR. The carbon-bearing reducing agent employed is gas-purification dust from aluminum production. Its composition is as follows: 21.00–43.27 wt % Al2O3, 18–27 wt % F, 8–13 wt % Na2O, 0.4–6.0 wt % K2O, 0.7–2.1 wt % CaO, 0.50–2.48 wt % SiO2, 2.1–2.3 wt % Fe2O3; 12.5–28.2 wt % Ctot; 0.03–0.90 wt % MnO, 0.04–0.90 wt % MgO, 0.09–0.46 wt % S, and 0.10–0.18 wt % P. The wire (diameter 5 mm) is produced on laboratory equipment. An ASAW 1250 system is used for surfacing, in the following conditions: Is = 400–450 A; Uarc = 32–36 V; Vs = 24–30 m/h. In surfacing, five metal layers are applied, under a layer of AN-26S flux and flux based on slag from silicomanganese production. The chemical composition of the applied metal is determined, and metallographic data are obtained: the size of the former austenite grain, the size of the martensite needles, and the content of nonmetallic inclusions are determined. Wear tests are conducted, and the hardness and microhardness are measured. The use of tungsten concentrate instead of tungsten powder in surfacing is shown to be possible in principle. The degree of tungsten extraction is calculated. For type-H wire, the replacement of tungsten powder by tungsten concentrate does not increase the content of nonmetallic inclusions in the metal layers applied; the primary austenite grain size is decreased. For type-E wire, the use of tungsten concentrate tends to decrease the primary austenite grain size and the size of the martensite needles and also increases the microhardness of martensite within the applied layer. The replacement of tungsten powder by tungsten concentrate in class-H wire considerably increases the hardness and wear resistance of the applied layer.



High-Temperature Melt Treatment in the Production of Heat-Resistant Alloys with a High Content of Foundry Wastes
摘要
Metallurgical wastes are used increasingly in alloy production. Given the great volume and age of the recovered material, the content of undesirable elements and nonmetallic inclusions in the batch tends to increase. That sharply impairs the structure and properties of the castings obtained. In turn, that is reflected in the polytherms of the melts’ physical properties and correspondingly the necessary smelting temperature and time for heat-resistant alloys. In the present work, the temperature dependence of the electrical resistivity, the kinematic viscosity, and the surface tension are studied for heat-resistant Ni–Nb–Cr–Mo melts. For EP902 alloy, the critical temperatures leading to irreversible changes that improve the state of the melt are established. The quantity of foundry wastes in the batch affects the temperature dependence of the melt’s physicochemical properties. With increase in the quantity of foundry wastes in smelting, the critical temperatures rise. The influence of the state of the melt on the solidification and structure of the hard metal is investigated. Solidification of EP902 alloy is studied by differential thermal analysis. It is found that solidification begins with the deposition of a solid solution based on γ phase and ends with the formation of a eutectic based on the intermetallide Ni3Nb. If the melt is heated above the critical temperatures, greater supercooling is observed but the eutectic temperature is practically unaffected. On the basis of the results for the melt’s physicochemical properties and its solidification, we propose high-temperature treatment of the melt to significantly improve the quality of castings obtained from heat-resistant alloys of EP902 type with a considerable content of foundry wastes in the batch. Experimental melts are subjected to mechanical tests with optimal high-temperature treatment of the melt. For melts containing 50% foundry waste, high-temperature treatment of the melt permits the production of castings with strength and plasticity that exceed the technical specifications and are consistent from melt to melt.



Thermal Stability of Ni3Al-Based Composite with Honeycomb Structure
摘要
By powder metallurgy, materials in the form of a single-phase alloy based on Ni3Al and the corresponding composite Ni3Al + W with honeycomb structure are produced. The structural unit of the composite is a round granule (mean size 25 μm) of nickel alloy surrounded by a continuous tungsten coating (thickness ~0.4 μm) applied by chemical gas-phase deposition. Compressive tests at room temperature show that the yield point of the composite Ni3Al + W at 20–1000°C exceeds that of the single-phase Ni3Al-based alloy (by a factor of as much as 1.7). However, at higher temperatures, the yield points of the alloy and composite are comparable. The unit yield point (standardized at a density of 7.8 g/cm3 for the alloy and 9.5 g/cm3 for the composite) behaves analogously. At 1300°C, the single-phase Ni3Al-based alloy exhibits solid–liquid behavior in compression. Creep tests with compression in vacuum at 1000–1200°C are conducted. By pair and parametric analysis of the creep processes according to Hollomon, regression equations for the creep rate, stress, and test temperature are obtained. The creep limit is calculated from the tolerances on the steady creep rate and its inverse. At all the test temperatures, the composite is characterized by lower creep rate (by a factor of seven) and higher creep limit (by a factor of 2.5) than for the nickel alloy on which it is based. The activation energy of creep is determined for the alloy and composite on the basis of an exponential relationship between the experimental quantities. The activation energy of creep for the nickel alloy is close to the activation energy of nickel self-diffusion in Ni3Al and materials based on it (230–310 kJ/mol). For the composite, it is close to the activation energy of tungsten self-diffusion (503 kJ/mol).



Decomposition of Supercooled Austenite in Low-Carbon Pipe Steel
摘要
Controlled rolling may facilitate the transition from ferrite–pearlite structure to bainite structure and hence improve the strength of low-carbon alloy steel. A literature review shows the lack of detailed research regarding the type of bainite structure that ensures optimal properties of low-carbon alloy steel. To determine the temperature, time, and other parameters of treatment to produce such structure, it is expedient to establish the influence of the cooling rate on the structure and properties of low-carbon alloy steel. In the present work, we investigate the decomposition of supercooled austenite in low-carbon alloy pipe steel with 0.062% C, 1.80% Mn, 0.120% Mo, 0.032% Cr, 0.90% Ni, and other elements (Al, Cu, V, Nb, Ti). The treatment conditions producing bainite structure with elevated steel are determined for such steel. At low cooling rates (no more than 6°C/s), not only ferrite is formed in the microstructure but also granular (or globular) bainite consisting of bainitic α phase and an insular martensite–austenite component (1–6 μm). At a rate of 6°C/s, transition to rack bainite is observed; around the boundaries of the racks, carbides and residual austenite are seen. At cooling rates above 16°C/s, the bainite has packet–rack structure, Between 50 and 150°C/s, the mean rack width of the bainitic α phase declines from 2.24 to 1.32 μm.



Assessing the Gas Permeability of the Cohesive Zone in the Blast Furnace
摘要
A mathematical model is proposed for assessing the gas permeability of the cohesive zone in the blast furnace. The gas permeability is improved by increasing the intensity of the axial gas flux and introducing coke nuts in the ore layer. This is important in introducing intense pulverized-coal injection.



Decision-Making Support in Blast-Furnace Operation
摘要
A model system for decision-making support (a model of the blast-furnace process developed at Yeltsin Ural Federal University and PAO MMK) is considered. The basic model modules permit calculation of the material and thermal balances, simulation of the thermal, slag, and gas-dynamic conditions in the blast furnace, and selection of the batch composition. The model system, embodied as software, is integrated into the PAO MMK information system. The model for calculating the material and thermal balances permits determination of the Fe, S, Mn, and Ti balances. Introduction of the Slag Conditions software permits identification of the most important slag property to ensure normal slag conditions; determination of the ratio of the iron-ore materials so that the slag has the best viscosity and viscosity gradient; and the production of hot metal of the required quality. The introduction of Blast-Furnace Gas Dynamics software permits calculation and visual mapping of the gas-dynamic characteristics of the batch bed and assessment of the change in pressure difference and equilibration of the batch within individual zones of the furnace in the design period, with variation in the batch parameters and properties. The results obtained in practical use of this system are outlined. Recommendations are made regarding the solution of industrial problems.



Piercing of Continuous-Cast Billet on Two-Roller Screw Mills with Liners
摘要
In billet piercing on two-roller screw mills, the influence of the shape and position of the liner (guide piece) on the ratio of the transverse and longitudinal deformation is analyzed. The quality of the sleeve obtained from the continuous-cast billet is ensured by simulating the parameters of the deformation region so as to increase the proportion of transverse deformation. In the piercing mill, the rollers consist of two conical sections, with a gorge between the cones. A piercing mandrel is mounted between the rollers. The tip of the mandrel projects from the gorge toward the input to the deformation region. Liners (guide pieces) limit the transverse motion. The liners consist of a conical input section, an output section, and an intermediate collar. The proportion of transverse deformation is increased by adjusting the distribution of oval distortion of the blank over the length of the deformation region.



Production of Capillary Pipe for Single-Use Medical Syringes
摘要
Production technology is developed for capillary pipe used in disposable medical syringes. The heat treatment of the pipe in pure hydrogen with inert-gas injection is described. In industrial research, the annealing of the capillary pipe in an electrical furnace is optimized. The temperature field within the muffle furnace is analyzed. The optimal flow rate of protective gas and the limiting permissible flow rate of the injected gas (nitrogen and argon) are determined. The mechanical properties of the pipes (blanks) welded at Tyumen Medical-Supply Plant and manufactured at Pervouralsk New Pipe Plant (PNTZ) are studied. When using nitrogen as the protective gas instead of hydrogen, the likelihood of obtaining clean pipe surfaces is greatly increased.



Visualizing the Fine Structure of Surface Bainite Layers on the Basis of EBSD Data
摘要
Electron backscatter diffraction (EBSD) is widely used to investigate the mutual crystallographic orientation in the structural components of steel, including bainite. Nevertheless, the fine structure of bainite (subplates and plates, packet components) is not investigated by that means. A method is proposed for visualization of the surface structure of bainitic structural steel by means of the Euler angles determined by EBSD. For the example of 25G2S2N2MA steel, a three-dimensional map of the bainite substructure is obtained. This result agrees with data obtained by scanning-probe microscopy.



Influence of Nonmetallic Inclusions on the Failure of Cast Stainless Steels
摘要
The structure of high-strength 09Kh16N4BL and 14Kh17N2L stainless steels produced by casting on fusible models is studied. The influence of the steel composition on the content of nonmetallic inclusions in the cast steel is of considerable interest. The morphology of the nonmetallic inclusions is studied, and they are identified. Fractographic analysis shows that the nonmetallic inclusions affect the failure of the stainless steels. Two methods are used for quantitative assessment of that influence. Besides the classical methods, multifractal parameterization of the structure is employed to study the structure of the stainless steels. On that basis, correlations are established between the main multifractal parameters and the mechanical properties of the steel.



Creation of a Wear-Resistant Tungsten-Carbide Surface Layer on Carbon Steels by Implantation and Electromechanical Machining
摘要
The formation of a wear-resistant surface layer by the implantation of materials based on tungsten carbide is considered. The influence of implanted tungsten-carbide powder on the formation of wear-resistant gradient structures at the frictional surfaces during electromechanical machining is studied. Thermomechanical processes in the plastic-deformation zone result in intense austenitization of the steel, with the solution of tungsten-carbide powder and the formation of highly disperse composite structures on disintegration of the supercooled austenite supersaturated with tungsten.



Steel Production from Metal-Bearing Waste
摘要
Analysis of two-stage iron and steel production by means of a blast furnace and an oxygen converter reveals its advantages and disadvantages. The main disadvantage is that carburization and decarburization of the metal are opposing processes and generate large quantities of waste with relatively high iron content. The organization of reduction and smelting of such waste—for the example of converter sludge—shows that direct reduction of iron by solid carbon, without carburization, is possible. Ore–coal pellets are produced experimentally. Their subsequent reduction and smelting yields metal ingots with the composition of steel.


