Cationic Oligomerization of the Pyrolysis C5 Fraction
- Авторы: Rozentsvet V.A.1, Kozlov V.G.1, Sablina N.A.1, Nesterov V.N.1, Fedorova Z.D.2, Munasypov D.N.2, Kiryukhin A.M.2
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Учреждения:
- Institute of Ecology of the Volga River Basin
- OOO Salavatnefteorgsintez Research and Development Center
- Выпуск: Том 58, № 8 (2018)
- Страницы: 694-701
- Раздел: Article
- URL: https://ogarev-online.ru/0965-5441/article/view/180330
- DOI: https://doi.org/10.1134/S0965544118080200
- ID: 180330
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Аннотация
The cationic oligomerization of the pyrolysis C5 fraction in the presence of catalyst systems based on AlCl3, VOCl3, BF3 · O(C2H5)2, and a Gustavson complex has been investigated. It has been shown that the use of the diisopropyl ether-modified Gustavson complex in the reaction makes it possible to synthesize fully soluble oligomers in high yields. The conversions of all the unsaturated components of the pyrolysis fraction to the oligomer at different durations of the oligomerization process have been determined. The synthesized oligomers are characterized by high unsaturation and exhibit the properties of film-forming compounds.
Об авторах
V. Rozentsvet
Institute of Ecology of the Volga River Basin
Автор, ответственный за переписку.
Email: rozentsvet@mail.ru
Россия, Togliatti, Samara oblast, 445003
V. Kozlov
Institute of Ecology of the Volga River Basin
Email: rozentsvet@mail.ru
Россия, Togliatti, Samara oblast, 445003
N. Sablina
Institute of Ecology of the Volga River Basin
Email: rozentsvet@mail.ru
Россия, Togliatti, Samara oblast, 445003
V. Nesterov
Institute of Ecology of the Volga River Basin
Email: rozentsvet@mail.ru
Россия, Togliatti, Samara oblast, 445003
Z. Fedorova
OOO Salavatnefteorgsintez Research and Development Center
Email: rozentsvet@mail.ru
Россия, Salavat, 453256 Bashkortostan
D. Munasypov
OOO Salavatnefteorgsintez Research and Development Center
Email: rozentsvet@mail.ru
Россия, Salavat, 453256 Bashkortostan
A. Kiryukhin
OOO Salavatnefteorgsintez Research and Development Center
Email: rozentsvet@mail.ru
Россия, Salavat, 453256 Bashkortostan
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