Synthesis of Benzoic and Phenylacetate Diesters Based on 8-Acetoxy and 8-Acetoxymethyltetracyclododec-3-Ene

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Abstract

The addition reaction of benzoic and phenylacetic acids to 5-acetoxy- and 5-acetoxymethyltetracyclo[4.4.1^2,5.1^7,10.0^1,6]dodec-3-ene in the presence of a catalyst, BF₃·O(C₂H₅)₂, was studied. As a result, mixed benzoate–phenylacetate diesters of tetracyclo[4.4.1^2,5.1^7,10.0^1,6]dodecanediol and 2-hydroxytetracyclo[4.4.1^2,5.1^7,10.0^1,6]dodec-8-ylmethanol were synthesized in yields of 73–80%. The structures of the obtained diesters were confirmed by IR spectroscopy and ^1H and ^13C NMR spectroscopy. Their physicochemical properties were investigated.

About the authors

V. S. Kadyrlya

Y.H. Mammadaliyev Institute of Petrochemical Processes of Ministry of Science and Education Republic of Azerbaijan

Email: qedirlivusale@mail.ru
prosp. Khojaly, 30, Baku, Az1025 Azerbaijan

E. G. Makhmudova

Y.H. Mammadaliyev Institute of Petrochemical Processes of Ministry of Science and Education Republic of Azerbaijan

Email: qedirlivusale@mail.ru
prosp. Khojaly, 30, Baku, Az1025 Azerbaijan

R. A. Rasulova

Y.H. Mammadaliyev Institute of Petrochemical Processes of Ministry of Science and Education Republic of Azerbaijan

Email: qedirlivusale@mail.ru
prosp. Khojaly, 30, Baku, Az1025 Azerbaijan

I. R. Safarova

Y.H. Mammadaliyev Institute of Petrochemical Processes of Ministry of Science and Education Republic of Azerbaijan

Email: qedirlivusale@mail.ru
prosp. Khojaly, 30, Baku, Az1025 Azerbaijan

Kh. M. Mamedova

Y.H. Mammadaliyev Institute of Petrochemical Processes of Ministry of Science and Education Republic of Azerbaijan

Email: qedirlivusale@mail.ru
prosp. Khojaly, 30, Baku, Az1025 Azerbaijan

M. D. Ibrahimova

Y.H. Mammadaliyev Institute of Petrochemical Processes of Ministry of Science and Education Republic of Azerbaijan

Email: qedirlivusale@mail.ru
prosp. Khojaly, 30, Baku, Az1025 Azerbaijan

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