One-Electron Transfer in the Reaction of Red Phosphorus with 4-Phenylthiobenzophenones in Superbasic Systems MOH/DMSO

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Abstract

Red phosphorus reacts with 4-phenylthio- and bis(4-phenylthio)benzophenones in superbase suspensions MOH/DMSO (M = Na, K) under heating (85°C, 1.5–4 h, Ar) according to the one-electron transfer mechanism: the formation of an anion radical of bis[phenyl(4-(phenylthio)phenyl)methyl] potassium phosphate is detected by EPR. Products of reduction of the initial phenylthiobenzophenones (functional diarylmethanols and diarylmethanes with phenylthio groups) and diphenyl disulfide were isolated from the reaction mixtures, and bis[phenyl(4-(phenylthio)phenyl)methyl]- and bis[di(4-(phenylthio)phenyl)methyl]potassium phosphates were identified (NMR).

About the authors

V. A Kuimov

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: vladimir_kuimov@irioch.irk.ru
ORCID iD: 0000-0001-8230-0266
Irkutsk, Russia

R. I Fattakhov

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

ORCID iD: 0009-0000-1037-0986
Irkutsk, Russia

N. I Tikhonov

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

ORCID iD: 0000-0002-5078-7150
Irkutsk, Russia

N. A Belogorlova

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

ORCID iD: 0000-0002-4883-8289
Irkutsk, Russia

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