Synthesis and Structure of Cyclopentadienylmolybdenum Tricarbonylate Complexes of Y3+ and Yb2+

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Abstract

The heterobimetallic complex [(GiPr)2Y(m2-CO)2MoCp(CO)2]2 (1) was obtained by the salt metathesis reaction of equimolar amounts of the yttrium bis-guanidinate chloride complex (GiPr)2Y(μ-Cl)2Li(THF)2 and Na[CpMo(CO)3] in a yield of 72%. The reaction of the monoamidinide bisalkyl derivative of yttrium AmdY(CH2SiMe3)2(THF) with two equivalents of molybdenum hydride CpMo(CO)3H, accompanied by the elimination of SiMe4, also made it possible to obtain the heterobimetallic complex [AmdY(THF)2{(m2-CO)MoCp(CO)2(μ2-CO)MoCp(CO)}2] (2), the yield of which was 66%. Using the interaction of the naphthalene complex (C10H8)Yb(THF)2 with CpMo(CO)3H in a molar ratio of 1:2 it was shown that the method can also be used to synthesize the heterobimetallic complex of divalent ytterbium [Yb(THF)4{(m2-CO)MoCp(CO)3}2]n (3). X-ray analysis revealed that complexes 1-3 contain a tetranuclear heterobimetallic skeleton Ln2Mo2 in which the Y3+ or Yb2+ ions are linked to molybdenum ions by bridging isocarbonyl groups, while complex 3 is a coordination polymer.

About the authors

D. M Lyubov

G.A. Razuvaev Institute of Organometallic Chemistry, RAS

Nizhny Novgorod, Russia

A. V Cherkasov

G.A. Razuvaev Institute of Organometallic Chemistry, RAS

Nizhny Novgorod, Russia

A. A Trifonov

G.A. Razuvaev Institute of Organometallic Chemistry, RAS; A.N. Nesmeyanov Institute of Elemento-Organic Compounds, RAS

Email: trif@iomc.ras.ru
Nizhny Novgorod, Russia; Moscow, Russia

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