Bimetallic (Co, Fe, Ni)Mg4Al2On layered double hydroxides based catalysts for the process of ammonia decomposition

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Abstract

In this work, monometallic MMg4Al2On and bimetallic MxMyMg4Al2On (M – Co,Fe, Ni) layered double hydroxides based catalysts were synthesized by the coprecipitation method. It was found that the samples dried at 110°C are layered double hydroxides with a hydrotalcite structure. After calcination at 550°C, the samples form mixed oxides with a specific nanostructure, intermediate between the NaCl and spinel type structures. The samples are characterized by a high specific surface area (105–209 m2/g). The catalytic activity was studied in the ammonia decomposition process. Among all the catalysts, the Co0.5Ni0.5Mg4Al2On catalyst has the highest activity: at 550°C and GHSV 72000 mL h−1 gcat −1 ammonia conversion was 32%, which corresponds to H2 productivity of 25.7 mmol gcat −1 min−1. According to the TEM, it was found that the average size of metal particles in the Co0.5Ni0.5Mg4Al2On catalyst is 10–14 nm. The Co0.5Ni0.5Mg4Al2On catalyst showed stable activity during the all testing period in the ammonia decomposition process (~40 h).

About the authors

Z. A Fedorova

Boreskov Institute of Catalysis SB RAS; Institute of Solid State Chemistry and Mechanochemistry SB RAS

Email: sabirova@catalysis.ru
Novosibirsk, Russia; Novosibirsk, Russia

V. A Borisov

New Chemical Technologies Center, Boreskov Institute of Catalysis SB RAS

Omsk, Russia

B. Abbas

Novosibirsk State University

Novosibirsk, Russia

V. P Pakharukova

Boreskov Institute of Catalysis SB RAS

Novosibirsk, Russia

E. Yu Gerasimov

Boreskov Institute of Catalysis SB RAS

Novosibirsk, Russia

A. Yu Gladkiy

Boreskov Institute of Catalysis SB RAS

Novosibirsk, Russia

D. A Shlyapin

Boreskov Institute of Catalysis SB RAS

Novosibirsk, Russia

P. V Snytnikov

Boreskov Institute of Catalysis SB RAS

Novosibirsk, Russia

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