CONDUCTIVITY OF MEDIUM LITHIUM SALT OF CALIX[ N ]ARENE SULFONIC ACID PLASTICIZED WITH PROPYLENE CARBONATE

A. A Knyazeva; Князева А. А; N. V Talagaeva; Талагаева Н. В; L. V Shmygleva; Шмыглева Л. В; А. А Lochina; Лочина А. А; G. V Nechaev; Нечаев Г. В; A. N Lapshin; Лапшин А. Н; N. A Slesarenko; Слесаренко Н. А; A. V Ivanov; Иванов А. В; Е. А Sanginov; Сангинов Е. А; V. M Freiman; Фрейман В. М; A. S Starikov; Стариков А. С; A. V Vinyukov; Винюков А. В

doi:10.7868/S3034618525090029

CONDUCTIVITY OF MEDIUM LITHIUM SALT OF CALIX[N]ARENE SULFONIC ACID PLASTICIZED WITH PROPYLENE CARBONATE

Authors: Knyazeva A.A¹, Talagaeva N.V¹, Shmygleva L.V¹, Lochina А.А¹, Nechaev G.V¹, Lapshin A.N¹, Slesarenko N.A¹, Ivanov A.V¹, Sanginov Е.А¹, Freiman V.M¹, Starikov A.S¹, Vinyukov A.V¹
Affiliations:
1. Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
Issue: Vol 61, No 9 (2025)
Pages: 443-449
Section: Regular articles
URL: https://ogarev-online.ru/0424-8570/article/view/376644
DOI: https://doi.org/10.7868/S3034618525090029
ID: 376644

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Abstract

It was discovered earlier that the calix[n]arene sulfonic acids have a record high proton conductivity, so that it was suggested that lithium salts of calix[n]arene sulfonic acids plasticized with aprotic solvents should also have ionic conductivity. It was found that the medium salt of calix[n]arene sulfonic acid in combination with propylene carbonate as a plasticizer has an ionic conductivity of 10^–1–10^–2 mS/cm, which makes it a promising material for further study and use as an electrolyte for lithium-ion batteries.

Keywords

металл-ионные аккумуляторы, твердотельные электролиты, каликс[n]арен, ионная проводимость, пропиленкарбонат

References

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