Synthesis and application of chelated complexes [Zn(L-arg)2(H2O)] and [[Zn(L-arg)2(H2O)](SO4)]2– as chiral selectors

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Abstract

By interaction of compounds Zn(II) and L-arginine (L-Arg) the chelated complexes [Zn(L-arg)2(H2O)] (I) and [[Zn(L-arg)2(H2O)](SO4)]2– (II) (L-arg is a deprotonated form of L-Arg) were synthesized. The structure of the obtained complexes was established by IR spectroscopy by comparing the experimental and theoretical IR spectra using quantum chemical modeling. Complexes I and II were studied as chiral selectors of enantioselective voltammetric sensors. It was shown that I exhibits better enantioselective compared to II. By DFT method, it was found that the difference in the exhibited enantioselectivity of complexes I and II can be due of the geometric isomerism of chelate compounds and the peculiarities of the coordination of the obtained complexes with the analyte molecule.

About the authors

R. R. Gizatov

Ufa University of Science and Technology

Author for correspondence.
Email: berestovatv@gmail.com
Ufa, Russia

Yu. B. Teres

Ufa University of Science and Technology

Email: berestovatv@gmail.com
Ufa, Russia

M. N. Galimov

Ufa University of Science and Technology

Email: berestovatv@gmail.com
Ufa, Russia

E. O. Bulysheva

Ufa University of Science and Technology

Email: berestovatv@gmail.com
Ufa, Russia

T. V. Berestova

Ufa University of Science and Technology

Email: berestovatv@gmail.com
Ufa, Russia

R. A. Zilberg

Ufa University of Science and Technology

Email: berestovatv@gmail.com
Ufa, Russia

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