New 2D coordination polymer of cobalt(II) pivalate with 1,4-diaminobutane: synthesis and thermal properties

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Abstract

The reaction of cobalt(II) trimethyl acetate (pivalate) [Co(Рiv)2]n (HРiv = HO2CCMe3) with 1,4-diaminobutane (Dab) in absolute acetonitrile gave a 2D-coordination polymer [Co(Piv)2(Dab)2]n (I) with an admixture of the co-product, but the addition of one equivalent of 2,2´-bipyridine to the reaction mixture made it possible to isolate a single-phase sample of I (according to X-ray diffraction data) with a yield of 78%. The crystal structure of I was determined by X-ray diffraction (CCDC No. 2404406): cobalt(II) atoms in a distorted octahedral environment (CoN4O2) of two monodentate carboxylate groups and four bridging Dab molecules form a layered coordination polymer with a honeycomb-like hcb topology. The thermal behavior of I was studied by synchronous thermal analysis: thermal decomposition leads to the formation of the organic salt (H2Dab)(Piv)2, cobalt(II) pivalate, and the octanuclear complex [Co8O2(Piv)12] — the products were identified by XRD and NMR spectroscopy.

About the authors

V. A. Bushuev

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; Higher School of Economics, National Research University

Email: yambulatov@yandex.ru
Moscow, Russia; Moscow Russia

D. S. Yambulatov

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: yambulatov@yandex.ru
Moscow, Russia

N. V. Gogoleva

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: yambulatov@yandex.ru
Moscow, Russia

F. V. Dolgushin

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: yambulatov@yandex.ru
Moscow, Russia

I. V. Skabitsky

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: yambulatov@yandex.ru
Moscow, Russia

S. S. Shapovalov

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: yambulatov@yandex.ru
Moscow, Russia

S. A. Nikolaevskii

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: yambulatov@yandex.ru
Moscow, Russia

M. A. Kiskin

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: yambulatov@yandex.ru
Moscow, Russia

I. L. Eremenko

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: yambulatov@yandex.ru
Moscow, Russia

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