Synthesis of nickel(II) complex with 2,6-dichlorophenyl-substituted pyridylpyrazole

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Abstract

The mononuclear nickel(II) complex [L2Ni(CH3OH)]Cl (I) was synthesized by the interaction of new ligand 2-(2,6-dichlorophenyl)-5-(pyridin-2-yl)-2,4-dihydro-3H-pyrazol-3-one (L) with nickel(II) chloride. The solvate of complex I with methanol [L2Ni(CH3OH)]Cl·3CH3OH and the initial ligand L were characterized by X-ray diffraction analysis (CCDC № 2314989 (I), 2314988 (L)). It was observed that ligand L exists in the pyrazolone form based on 1H NMR data, whereas in complex I, it is found in the pyrazolol form according to X-ray diffraction data. Complex I is a unique example of a pyrazolol complex in which the oxygen atom does not engage in coordinating with the transition metal ion to create the coordination polymer.

About the authors

I. A. Nikovskii

Nesmeyanov Institute of Organoelement Compounds

Email: igornikovskiy@mail.ru
Moscow, Russia

E. S. Safiullina

Nesmeyanov Institute of Organoelement Compounds

Email: igornikovskiy@mail.ru
Moscow, Russia

Yu. V. Nelyubina

Nesmeyanov Institute of Organoelement Compounds; Moscow Institute of Physics and Technology

Author for correspondence.
Email: igornikovskiy@mail.ru
Moscow, Russia; Dolgoprudny, Moscow Region, Russia

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