Rhenium(V) Tris(pyrazolyl)borate Complexes as Ligands in Square Planar Palladium and Platinum Complexes

I. V. Skabitskii; Скабицкий И. В.; Yu. Ya. Il’ina; Ильина Ю. Я.; S. S. Shapovalov; Шаповалов С. С.

doi:10.31857/S0132344X22700086

Rhenium(V) Tris(pyrazolyl)borate Complexes as Ligands in Square Planar Palladium and Platinum Complexes

Authors: Skabitskii I.V.¹, Il’ina Y.Y.¹, Shapovalov S.S.¹
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia
Issue: Vol 49, No 1 (2023)
Pages: 36-43
Section: Articles
URL: https://ogarev-online.ru/0132-344X/article/view/137263
DOI: https://doi.org/10.31857/S0132344X22700086
EDN: https://elibrary.ru/ESDZQX
ID: 137263

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Abstract

The reactions of TpReO(SnC3H7)2 (Tp = tris(pyrazolyl)borate anion) with acetonitrile complexes PdCl2(MeCN)2 and PtI2(MeCN)2 in toluene solutions resulted in the formation of new heterometallic rhenium complexes TpReO(µ-SnC3H7)2MX2 (MX2 = PdCl2 (I), MX2 = PtI2 (II)). A similar complex TpReO(µ-SnC3H7)2PdI2 (III) was formed either on treatment of I with NaI in dichloromethane or in the reaction of TpReO(SnC3H7)2 with a suspension of PdI2 in toluene. Complexes I–III were characterized by IR and NMR spectroscopy and by X-ray diffraction (CCDC nos. 2172225–2172227).

Keywords

rhenium complexes, thiolate complexes, heterometallic complexes, tris(pyrazolyl)borate, X-ray diffraction

References

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