GIDRIROVANIE SO2 S ISPOL'ZOVANIEM Cu/Zn-KATALIZATOROV NA OSNOVE PORISTYKh AROMATIChESKIKh KARKASOV

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Abstract

Углекислый газ представляет собой перспективный реагент для синтеза широкого круга ценных химических продуктов, в частности метанола. В настоящей работе впервые на основе как немодифицированных, так и модифицированных аминогруппами пористых ароматических каркасов синтезированы Cu/Zn-катализаторы для гидрирования CO2 в метанол. Рассмотрена взаимосвязь текстурных характеристик носителя и формирующихся в его структуре наночастиц активной фазы. Активность синтезированных в работе катализаторов исследована при 250°C и 40 атм (CO2/H2 = 1:3). Определен оптимальный состав катализатора, изучено влияние природы растворителя на его активность.

About the authors

D. A Makeeva

Author for correspondence.
Email: daria.makeeva@chemistry.msu.ru
ORCID iD: 0000-0001-7750-7457

A. L Maksimov

Email: daria.makeeva@chemistry.msu.ru
ORCID iD: 0000-0001-9297-4950

д.х.н., проф., акад. РАН

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