Europium Complexes with Fluorinated Carbazole-Containing Tetraketones

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Abstract

Complex compounds of fluorine-containing tetraketones on the basis of carbazole with europium(III) ions were synthesized, the luminescence-spectral properties of the obtained complexes were evaluated and the exact stoichiometric composition was established. The position of the maximum in the excitation spectrum (≥370 nm) of the complexes, a significant Stokes shift (>250 nm), and a long lifetime of the excited state (400-700 μs) allow us to consider the synthesized complexes as potential reagents for time-resolved fluorescence immunoassay.

About the authors

A. G. Shubina

State University of Education

Email: shubina.anna98@yandex.ru
Moscow, Russia

T. S. Kostryukova

State Research Institute of Biological Instrumentation

Moscow, Russia

D. E. Pugachev

State Research Institute of Biological Instrumentation

Moscow, Russia

D. V. Paramonov

State Research Institute of Biological Instrumentation

Moscow, Russia

S. Z. Vatsadze

Zelinsky Institute of Organic Chemistry

Moscow, Russia

N. V. Vasiliev

State University of Education; State Research Institute of Biological Instrumentation

Moscow, Russia; Moscow, Russia

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