SYNTHESIS OF THE STABLE NiFe2O4 AND NiFe2O4/Au HYDROSOLS USING POLYETHYLENIMINE

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Abstract

In this study, the effect of reaction parameters on the stabilization of nickel ferrite hydroxols in the presence of polyethylenimine (PEI) was determined using the design of experiment (DOE) method. In the optimal conditions, a nickel ferrite hydroxol was obtained, and its sedimentation stability was maintained for two months. A NiFe2O4/Au hybrid material was obtained by adsorbing on the surface of magnetic gold particles and reducing Au(III) by hydroxylamine in the presence of PEI, over four steps. Transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS) show the NiFe2O4/Au material is Au0 nanoparticles 4 nm in size and uniformly distributed on the surface of ferrite nickel nanoparticles 9.7 nm in size. The gold particles are firmly attached to the surface of nickel ferrite and do not separate during post-synthetic and ultrasonic treatment. Besides their content can be controlled by adjusting the number of gold reduction stages.

About the authors

S. V Saikova

Siberian Federal University; Institute of Chemistry and Chemical Engineering, Krasnoyarsk Scientific Center (Federal Research Center), Siberian Branch, Russian Academy of Sciences

Krasnoyarsk, Russia; Krasnoyarsk, Russia

D. I Nemkova

Siberian Federal University

Krasnoyarsk, Russia

A. E Krolikov

Siberian Federal University

Email: antonkrolikov@mail.ru
Krasnoyarsk, Russia

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